d-Mannose

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-301.95 ± 0.30kcal/molCcbWu, Finch, et al., 1987ALS
Quantity Value Units Method Reference Comment
Δcsolid-672.24 ± 0.22kcal/molCcbWu, Finch, et al., 1987Corresponding Δfsolid = -301.953 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-672.33 ± 0.81kcal/molCcbStroh and Fincke, 1963Corresponding Δfsolid = -301.87 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
51.6303.Kawaizumi, Kushida, et al., 1981T = 300 to 315 K.; DH
51.20300.Kawaizumi, Nishio, et al., 1981T = 270 to 325 K. Cp given as 1.19 J/g*K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Sodium ion (1+) + d-Mannose = (Sodium ion (1+) • d-Mannose)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
Δr42.8kcal/molCIDCCerda and Wesdemiotis, 1999 

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference
0.0298.CIDCCerda and Wesdemiotis, 1999

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Sodium ion (1+) + d-Mannose = (Sodium ion (1+) • d-Mannose)

By formula: Na+ + C6H12O6 = (Na+ • C6H12O6)

Quantity Value Units Method Reference Comment
Δr42.8kcal/molCIDCCerda and Wesdemiotis, 1999 

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference
0.0298.CIDCCerda and Wesdemiotis, 1999

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA
Source reference COBLENTZ NO. 2855
Date Not specified, most likely prior to 1970
Name(s) hexopyranose
State SOLID (MINERAL OIL MULL)
Instrument Not specified, most likely a prism, grating, or hybrid spectrometer.
Path length
SPECTRAL CONTAMINATION DUE TO OIL AROUND 2900 CM-1
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY
Melting point 128.5 C

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin RADIAN CORP
NIST MS number 76401

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu, Finch, et al., 1987
Wu, D.; Finch, A.; Gardner, P.J., Standard energy of combustion and enthalpy of formation of α-D-mannose, Wuhan Daxue Zuebao, Ziran Kexueban, 1987, 59-63. [all data]

Stroh and Fincke, 1963
Stroh, H.H.; Fincke, C.R., Beobachtung ciner unterschidlichen hydrierbarkeit von n-substituiertten aziridin-derivaten, Z. Chem., 1963, 3, 265-266. [all data]

Kawaizumi, Kushida, et al., 1981
Kawaizumi, F.; Kushida, S.; Miyahara, Y., Determination of the specific heat capacities of aqueous solutions of pentose, Bull. Chem. Soc. Japan, 1981, 54(8), 2282-2285. [all data]

Kawaizumi, Nishio, et al., 1981
Kawaizumi, F.; Nishio, N.; Nomura, H.; Miyahara, Y., Heat-capacity measurements of aqueous solutions of mono-, di-, and tri-saccharides using an isoperibol twin calorimeter, J. Chem. Thermodynam., 1981, 13, 89-98. [all data]

Cerda and Wesdemiotis, 1999
Cerda, B.A.; Wesdemiotis, C., Thermochemistry and Structures of Na+ Coordinated Mono- and Disaccharide Stereoisomers, Int. J. Mass Spectrom., 1999, 189, 2-3, 189, https://doi.org/10.1016/S1387-3806(99)00085-8 . [all data]


Notes

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