d-Mannose

• Formula: C₆H₁₂O₆
• Molecular weight: 180.1559
• IUPAC Standard InChI: InChI=1S/C6H12O6/c7-1-3(9)5(11)6(12)4(10)2-8/h1,3-6,8-12H,2H2/t3-,4-,5-,6-/m1/s1 Copy

  
• IUPAC Standard InChIKey: GZCGUPFRVQAUEE-KVTDHHQDSA-N Copy
• CAS Registry Number: 3458-28-4
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Stereoisomers:
  • D-gulose
  • Glucose
  • D-Galactose
• Other names: Mannose, d-; Carubinose; d(+)-Mannose; Mannose; Seminose
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Comments:
  • Although only a single structure is shown, this species may exist in several forms including a linear molecule and a six membered ring.
• Information on this page:
  • Condensed phase thermochemistry data
  • Reaction thermochemistry data
  • Ion clustering data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Options:
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ( • )

By formula: Na⁺ + C₆H₁₂O₆ = (Na⁺ • C₆H₁₂O₆)

Free energy of reaction

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Na⁺ + C₆H₁₂O₆ = (Na⁺ • C₆H₁₂O₆)

Free energy of reaction

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wu, Finch, et al., 1987
Wu, D.; Finch, A.; Gardner, P.J., Standard energy of combustion and enthalpy of formation of α-D-mannose, Wuhan Daxue Zuebao, Ziran Kexueban, 1987, 59-63. [all data]

Stroh and Fincke, 1963
Stroh, H.H.; Fincke, C.R., Beobachtung ciner unterschidlichen hydrierbarkeit von n-substituiertten aziridin-derivaten, Z. Chem., 1963, 3, 265-266. [all data]

Kawaizumi, Kushida, et al., 1981
Kawaizumi, F.; Kushida, S.; Miyahara, Y., Determination of the specific heat capacities of aqueous solutions of pentose, Bull. Chem. Soc. Japan, 1981, 54(8), 2282-2285. [all data]

Kawaizumi, Nishio, et al., 1981
Kawaizumi, F.; Nishio, N.; Nomura, H.; Miyahara, Y., Heat-capacity measurements of aqueous solutions of mono-, di-, and tri-saccharides using an isoperibol twin calorimeter, J. Chem. Thermodynam., 1981, 13, 89-98. [all data]

Cerda and Wesdemiotis, 1999
Cerda, B.A.; Wesdemiotis, C., Thermochemistry and Structures of Na+ Coordinated Mono- and Disaccharide Stereoisomers, Int. J. Mass Spectrom., 1999, 189, 2-3, 189, https://doi.org/10.1016/S1387-3806(99)00085-8 . [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  T	Temperature
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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