1-Hexanol, 3,5,5-trimethyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-109.2kcal/molCcbNicholson, 1960 
Quantity Value Units Method Reference Comment
Δcliquid-1420.5 ± 0.7kcal/molCcbNicholson, 1960Corresponding Δfliquid = -109.1 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil467.2KN/AWeast and Grasselli, 1989BS
Tboil463.15KN/AGresham, Brooks, et al., 1952Uncertainty assigned by TRC = 4. K; TRC
Tboil464.15KN/AFreedman and Becker, 1951Uncertainty assigned by TRC = 4. K; TRC
Tboil466.65KN/ABruner, 1949Uncertainty assigned by TRC = 4. K; TRC
Tboil466.05KN/AKeulemans, Kwantes, et al., 1948Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δvap16.2 ± 0.1kcal/molGSRoganov, Pisarev, et al., 2005Based on data from 288. to 324. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

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Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySE-301041.Vinogradov, 2004Program: not specified
CapillarySPB-51049.Begnaud, Pérès, et al., 200360. m/0.32 mm/1. μm; Program: not specified

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryCarbowax 20M1480.Vinogradov, 2004Program: not specified

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nicholson, 1960
Nicholson, G.R., 478. The heats of combustion of butanal and heptanal, J. Chem. Soc., 1960, 2377-2378. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Gresham, Brooks, et al., 1952
Gresham, W.F.; Brooks, R.E.; Bruner, W.M., , 1952. [all data]

Freedman and Becker, 1951
Freedman, R.W.; Becker, K., The reaction of grignard reagents with 3,4-epoxy-1-butene: II ethylmagnesium bromide and diethylmagnesium, J. Org. Chem., 1951, 16, 1701. [all data]

Bruner, 1949
Bruner, W.M., Ind. Eng. Chem. 41, 1949, 2860 1949. [all data]

Keulemans, Kwantes, et al., 1948
Keulemans, A.I.M.; Kwantes, A.; van Bavel, T., Recl. Trav. Chim. Pays-Bas, 1948, 67, 298. [all data]

Roganov, Pisarev, et al., 2005
Roganov, Gennady N.; Pisarev, Pavel N.; Emel'yanenko, Vladimir N.; Verevkin, Sergey P., Measurement and Prediction of Thermochemical Properties. Improved Benson-Type Increments for the Estimation of Enthalpies of Vaporization and Standard Enthalpies of Formation of Aliphatic Alcohols, J. Chem. Eng. Data, 2005, 50, 4, 1114-1124, https://doi.org/10.1021/je049561m . [all data]

Vinogradov, 2004
Vinogradov, B.A., Production, composition, properties and application of essential oils, 2004, retrieved from http://viness.narod.ru. [all data]

Begnaud, Pérès, et al., 2003
Begnaud, F.; Pérès, C.; Berdagué, J.-L., Characterization of volatile effluents of livestock buildings by solid-phase microextraction, Int. J. Environ. Anal. Chem., 2003, 83, 10, 837-849, https://doi.org/10.1080/03067310310001603349 . [all data]


Notes

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