D-Gluconic acid, 6TMS derivative
- Formula: C24H60O7Si6
- Molecular weight: 629.2420
- IUPAC Standard InChI: InChI=1S/C24H60O7Si6/c1-32(2,3)26-19-20(27-33(4,5)6)21(28-34(7,8)9)22(29-35(10,11)12)23(30-36(13,14)15)24(25)31-37(16,17)18/h20-23H,19H2,1-18H3/t20-,21-,22+,23-/m1/s1
- IUPAC Standard InChIKey: IVIMVRAMMWQMHJ-BXXSPATCSA-N
- CAS Registry Number: 34290-52-3
- Chemical structure:
This structure is also available as a 2d Mol file - Stereoisomers:
- Other names: D-Gluconic acid, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, trimethylsilyl ester; Gluconic acid, 2,3,4,5,6-pentakis-O-(trimethylsilyl)-, trimethylsilyl ester, D-; Trimethylsilyl 2,3,4,5,6-pentakis-O-(trimethylsilyl)gluconate, D-; Gluconic acid, (6TMS); Gluconic acid, hexakis-TMS; Gluconic acid, TMS, #2; Gluconic acid TMS; Gluconic acid, TMS, #1
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | OV-1 | 160. | 2068. | Petersson, 1977 | N2, Chromosorb G (100-120 mesh); Column length: 2. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | RTX-5Sil | 1997.0 | Wagner, Sefkow, et al., 2003 | 80. C @ 2. min, 18. K/min, 350. C @ 2. min; Column length: 30. m; Column diameter: 0.25 mm |
| Capillary | Ultra-2 | 2043. | Tuchman, Bowers, et al., 1984 | 25. m/0.31 mm/0.52 μm, He, 5. K/min; Tstart: 50. C; Tend: 300. C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5MS | 2037. | Lee, Yanamandra, et al., 2002 | 30. m/0.25 mm/0.25 μm, He, 70. C @ 3. min, 4. K/min, 280. C @ 3. min |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Petersson, 1977
Petersson, G.,
Retention Data in GLC Analysis; Carbohydrate-Related Hydroxy Carboxylic and Dicarboxylic Acids as Trimethylsilyl Derivatives,
J. Chromatogr. Sci., 1977, 15, 7, 245-255, https://doi.org/10.1093/chromsci/15.7.245
. [all data]
Wagner, Sefkow, et al., 2003
Wagner, C.; Sefkow, M.; Kopka, J.,
Construction and application of a mass spectral and retention time index database generated from plant GC/EI-TOF-MS metabolite profiles,
Phytochemistry, 2003, 62, 6, 887-900, https://doi.org/10.1016/S0031-9422(02)00703-3
. [all data]
Tuchman, Bowers, et al., 1984
Tuchman, M.; Bowers, L.D.; Fregien, K.D.; Crippin, P.J.; Krivit, W.,
Capillary Gas Chromatographic Separation of Urinary Organic Acids. Retention Indices of 101 Urinary Acids on a 5% Phenylmethyl Silicone Capillary Column,
J. Chromatogr. Sci., 1984, 22, 5, 198-202, https://doi.org/10.1093/chromsci/22.5.198
. [all data]
Lee, Yanamandra, et al., 2002
Lee, B.Y.; Yanamandra, K.; Thurmon, T.F.,
Quantitative estimation of organic analytes with a capillary column,
Am. Clin. Lab., 2002, May, 30-34. [all data]
Notes
Go To: Top, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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