2-(Ethylsulphonyl)-2-methylpropane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-491.4 ± 2.8kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -489. ± 2. kJ/mol; Hfusion=1.7±0.2 kcal/mol,Heat of comb. corrected for constant pressure

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-578.0 ± 1.4kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -575.4 ± 0.8 kJ/mol; Hfusion=1.7±0.2 kcal/mol,Heat of comb. corrected for constant pressure
Quantity Value Units Method Reference Comment
Δcsolid-4386.2 ± 1.3kJ/molCcbMackle and O'Hare, 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -4388.3 ± 0.4 kJ/mol; Hfusion=1.7±0.2 kcal/mol,Heat of comb. corrected for constant pressure

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tfus310.4KN/AMackle and O'Hare, 1961Uncertainty assigned by TRC = 0.8 K
Tfus306.2KN/AMcallan, Cullum, et al., 1951Uncertainty assigned by TRC = 0.5 K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mackle and O'Hare, 1961
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 5.-Heats of combustion, formation, fusion, vaporization and atomization of eleven aliphatic sulphones, Trans. Faraday Soc., 1961, 57, 1070-1074. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Mcallan, Cullum, et al., 1951
Mcallan, D.T.; Cullum, T.V.; Dean, R.A.; Fidler, F.A., The Preparation and Properties of Sulfur Compounds Related to Petroleum I. The Dialkyl Sulfides and Disulfides, J. Am. Chem. Soc., 1951, 73, 3627-32. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, References