Trimethylindium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δsub11.6 ± 0.60kcal/molN/APilcher and Skinner, 1983See also Clark and Price, 1968.; AC
Δsub11.6 ± 0.60kcal/molRSCDennis, Work, et al., 1934MS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
15.0294.N/AFulem, Ruzicka, et al., 2004Based on data from 274. to 313. K.; AC
13.8344.AStephenson and Malanowski, 1987Based on data from 328. to 362. K. See also Laubengayer and Gilliam, 1941.; AC

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.4178358.7Ur'yash, Ronina, et al., 1991DH
3.42358.7Ur'yash, Ronina, et al., 1991, 2AC

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin MUS30 A. Mujsce, AT&T Bell Labs., Murray Hill, N.J., USA
NIST MS number 115426

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References

Go To: Top, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Clark and Price, 1968
Clark, W.D.; Price, S.J.W., Determination of the heat of formation of trimethylindium and calculation of the mean In---CH 3 bond dissociation energy, Can. J. Chem., 1968, 46, 10, 1633-1634, https://doi.org/10.1139/v68-272 . [all data]

Dennis, Work, et al., 1934
Dennis, L.M.; Work, R.W.; Rochow, E.G.; Chamot, E.M., J. Am. Chem. Soc., 1934, 56, 1047. [all data]

Fulem, Ruzicka, et al., 2004
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Hulicius, E.; Simecek, T.; Pangrác, J.; Rushworth, S.A.; Smith, L.M., Measurement of vapour pressure of In-based metalorganics for MOVPE, Journal of Crystal Growth, 2004, 272, 1-4, 42-46, https://doi.org/10.1016/j.jcrysgro.2004.09.001 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Laubengayer and Gilliam, 1941
Laubengayer, A.W.; Gilliam, W.F., The Alkyls of the Third Group Elements. I. Vapor Phase Studies of the Alkyls of Aluminum, Gallium and Indium 1, J. Am. Chem. Soc., 1941, 63, 2, 477-479, https://doi.org/10.1021/ja01847a031 . [all data]

Ur'yash, Ronina, et al., 1991
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.D., Physicochemical study of alkyl derivatives of indium, Metalloorg. Khim., 1991, 4(5), 1050-1054. [all data]

Ur'yash, Ronina, et al., 1991, 2
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.V.; Kuznetsova, T.V.; Petrun, T.V.; Feshchenko, I.A.; Zorin, A.D., Physicochemical study of alkyl derivatives of indium, Metalloogranicheskaya Khimiya, 1991, 4, 5, 1050. [all data]


Notes

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