Trimethylindium
- Formula: C3H9In
- Molecular weight: 159.922
- IUPAC Standard InChIKey: IBEFSUTVZWZJEL-UHFFFAOYSA-N
- CAS Registry Number: 3385-78-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Indium, trimethyl-
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 11.6 ± 0.60 | kcal/mol | N/A | Pilcher and Skinner, 1983 | See also Clark and Price, 1968.; AC |
ΔsubH° | 11.6 ± 0.60 | kcal/mol | RSC | Dennis, Work, et al., 1934 | MS |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
15.0 | 294. | N/A | Fulem, Ruzicka, et al., 2004 | Based on data from 274. to 313. K.; AC |
13.8 | 344. | A | Stephenson and Malanowski, 1987 | Based on data from 328. to 362. K. See also Laubengayer and Gilliam, 1941.; AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
3.4178 | 358.7 | Ur'yash, Ronina, et al., 1991 | DH |
3.42 | 358.7 | Ur'yash, Ronina, et al., 1991, 2 | AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Clark and Price, 1968
Clark, W.D.; Price, S.J.W.,
Determination of the heat of formation of trimethylindium and calculation of the mean In---CH 3 bond dissociation energy,
Can. J. Chem., 1968, 46, 10, 1633-1634, https://doi.org/10.1139/v68-272
. [all data]
Dennis, Work, et al., 1934
Dennis, L.M.; Work, R.W.; Rochow, E.G.; Chamot, E.M.,
J. Am. Chem. Soc., 1934, 56, 1047. [all data]
Fulem, Ruzicka, et al., 2004
Fulem, M.; Ruzicka, K.; Ruzicka, V.; Hulicius, E.; Simecek, T.; Pangrác, J.; Rushworth, S.A.; Smith, L.M.,
Measurement of vapour pressure of In-based metalorganics for MOVPE,
Journal of Crystal Growth, 2004, 272, 1-4, 42-46, https://doi.org/10.1016/j.jcrysgro.2004.09.001
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Laubengayer and Gilliam, 1941
Laubengayer, A.W.; Gilliam, W.F.,
The Alkyls of the Third Group Elements. I. Vapor Phase Studies of the Alkyls of Aluminum, Gallium and Indium 1,
J. Am. Chem. Soc., 1941, 63, 2, 477-479, https://doi.org/10.1021/ja01847a031
. [all data]
Ur'yash, Ronina, et al., 1991
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.D.,
Physicochemical study of alkyl derivatives of indium,
Metalloorg. Khim., 1991, 4(5), 1050-1054. [all data]
Ur'yash, Ronina, et al., 1991, 2
Ur'yash, V.F.; Ronina, O.V.; Karataev, E.N.; Zimina, I.V.; Kuznetsova, T.V.; Petrun, T.V.; Feshchenko, I.A.; Zorin, A.D.,
Physicochemical study of alkyl derivatives of indium,
Metalloogranicheskaya Khimiya, 1991, 4, 5, 1050. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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