Hydroxyl radical

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas9.319kcal/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
gas,1 bar43.908cal/mol*KReviewChase, 1998Data last reviewed in June, 1977

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1300.1300. to 6000.
A 7.7145516.870701
B -2.7158011.126790
C 3.251781-0.194724
D -0.9193320.013085
E -0.000319-0.656747
F 7.1106916.313191
G 53.9145151.17510
H 9.3181319.318131
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1977 Data last reviewed in June, 1977

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

O- + Hydrogen cation = Hydroxyl radical

By formula: O- + H+ = HO

Quantity Value Units Method Reference Comment
Δr382.600 ± 0.010kcal/molD-EANeumark, Lykke, et al., 1985gas phase; Given: 1.461122(3) eV; revised to 1.4611107(17) eV, 95BLO, based on missing term+86CODATA
Quantity Value Units Method Reference Comment
Δr376.73 ± 0.15kcal/molH-TSNeumark, Lykke, et al., 1985gas phase; Given: 1.461122(3) eV; revised to 1.4611107(17) eV, 95BLO, based on missing term+86CODATA

Fluorine anion + Hydroxyl radical = HFO-

By formula: F- + HO = HFO-

Quantity Value Units Method Reference Comment
Δr32.4 ± 2.3kcal/molLPESDeyerl and Continetti, 2005gas phase; affinity at 0 K

Hydrogen anion + Hydroxyl radical = (Hydrogen anion • Hydroxyl radical)

By formula: H- + HO = (H- • HO)

Quantity Value Units Method Reference Comment
Δr51.8 ± 4.1kcal/molTherde Koening and Nibbering, 1984gas phase

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + Hydroxyl radical = HFO-

By formula: F- + HO = HFO-

Quantity Value Units Method Reference Comment
Δr32.4 ± 2.3kcal/molLPESDeyerl and Continetti, 2005gas phase; affinity at 0 K

Hydrogen anion + Hydroxyl radical = (Hydrogen anion • Hydroxyl radical)

By formula: H- + HO = (H- • HO)

Quantity Value Units Method Reference Comment
Δr51.8 ± 4.1kcal/molTherde Koening and Nibbering, 1984gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Neumark, Lykke, et al., 1985
Neumark, D.M.; Lykke, K.R.; Andersen, T.; Lineberger, W.C., Laser photodetachment measurement of the electron affinity of atomic oxygen, Phys. Rev. A:, 1985, 32, 1890. [all data]

Deyerl and Continetti, 2005
Deyerl, H.J.; Continetti, R.E., Photoelectron-photofragment coincidence study of OHF-: transition state dynamics of the reaction OH+F - O+HF, Phys. Chem. Chem. Phys., 2005, 7, 5, 855-860, https://doi.org/10.1039/b414604b . [all data]

de Koening and Nibbering, 1984
de Koening, L.J.; Nibbering, N.M.M., Formation of the Long-Lived H2O-. Ion in the Gas Phase, J. Am. Chem. Soc., 1984, 106, 25, 7971, https://doi.org/10.1021/ja00337a054 . [all data]


Notes

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