Pentafluoromethylamine
- Formula: CF5N
- Molecular weight: 121.0094
- CAS Registry Number: 335-01-3
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Gas phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -707. ± 3. | kJ/mol | Ccb | Walker, 1972 | Decompostion reaction |
Phase change data
Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
18.6 | 135. | Stephenson and Malanowski, 1987 | Based on data from 128. to 141. K. See also Fahim, Fleifel, et al., 1951. |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: CF5N = CF4 + 0.5N2 + 0.5F2
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -226. ± 2. | kJ/mol | Ccb | Walker, 1972 | gas phase; Decompostion reaction |
By formula: CF4 + 0.5N2 + 0.5F2 = CF5N
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 226. ± 2. | kJ/mol | Ccb | Walker, 1972 | gas phase; Decompostion reaction |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Walker, 1972
Walker, L.C.,
The enthalpy of decomposition of CF3NF2(g) to CF4(g), N2(g), and F2(g),
J. Chem. Thermodyn., 1972, 4, 219-223. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Fahim, Fleifel, et al., 1951
Fahim, Hussein A.; Fleifel, Abdallah M.; Coates, G.E.; Harris, J.; Sutcliffe, T.; Lane, E.S.; Lewis, K.G.; Hassall, C.H.; Martin, S.L.; Hilton, Marjorie L.; Webb, M.; McGookin, A.; Page, H.,
Notes,
J. Chem. Soc., 1951, 2761, https://doi.org/10.1039/jr9510002761
. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔfH°gas Enthalpy of formation of gas at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.