Endo-bicyclo[2.2.1]heptane-2-carbonitrile

• Formula: C₈H₁₁N
• Molecular weight: 121.1796
• IUPAC Standard InChI: InChI=1S/C8H11N/c9-5-8-4-6-1-2-7(8)3-6/h6-8H,1-4H2/t6?,7?,8-/m1/s1 Copy

  
• IUPAC Standard InChIKey: GAHKEUUHTHVKEA-KAVNDROISA-N Copy
• CAS Registry Number: 3211-87-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Stereoisomers:
  • 2-Norbornanecarbonitrile
  • Exo-bicyclo[2.2.1]heptane-2-carbonitrile
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• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • References
  • Notes
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of fusion

Entropy of fusion

Enthalpy of phase transition

Entropy of phase transition

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Goroshko, Kozina, et al., 1964
Goroshko, N.N.; Kozina, M.P.; Skuratov, S.M.; Belikova, N.A.; Plate, A.F., The heats of combustion of exo- and endo isomers of 2-cyano-bicyclo(2.2.1)heptane, Vestn. Mosk. Univ. Ser. 2: Khim., 1964, 19, 3-6. [all data]

Kolesov, Seregin, et al., 1970
Kolesov, V.P.; Seregin, E.A.; Belikova, N.A.; Skuratov, S.M.; Plate, A.F., Specific heat in the interval 12-350K and thermodynamic functions of the endo- and exo-isomers of 2-cyanobicyclo[2,2,1]heptane, Termodin. Termokhim. Konstanty, 1970, 1970, 164-172. [all data]

Seregin, Kolesov, et al., 1962
Seregin, E.A.; Kolesov, V.P.; Belikova, N.A.; Skuratov, S.M.; Plate, A.F., Heat capacity at low temperatures and the thermodynamic functions of endo- and exo-2-cyanobicyclo[2.2.1]heptane, Dokl. Akad. Nauk, 1962, SSSR 145(3), 580-583. [all data]

Kolesov, Seregin, et al., 1970, 2
Kolesov, V.P.; Seregin, E.A.; Belikova, N.A.; Skuratov, S.M.; Plate, A.F., Specific heat in the interval 12-350 K and thermodynamic functions of the endo- and exo-isomers of 2-cyanobicyclo[2.2.1]heptane, Termodin. Termokhim. Konstanty., 1970, 1970, 163-72. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Notes

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• Symbols used in this document:
  

  Cp,solid	Constant pressure heat capacity of solid
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  Ttriple	Triple point temperature
  ΔHtrs	Enthalpy of phase transition
  ΔStrs	Entropy of phase transition
  ΔcH°solid	Enthalpy of combustion of solid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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