7,14-Methano-4H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-4-one, 2,3,7,7a,8,9,10,11,13,14-decahydro-, [7S-(7α,7aβ,14α)]-


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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NIST MS number 11909

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-12128.Beuerle, 2010He, 6. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 150. C; Tend: 300. C
CapillaryOV-12132.Martins, Wink, et al., 2005He, 120. C @ 3. min, 8. K/min; Column length: 30. m; Column diameter: 0.25 mm; Tend: 300. C
CapillaryDB-52132.Przybylak, Ciesiolka, et al., 2005He, 180. C @ 2. min, 5. K/min, 300. C @ 10. min; Column length: 30. m; Column diameter: 0.25 mm
CapillaryDB-12132.Martínez-Herrera, Robledo-Quintos, et al., 200130. m/0.25 mm/0.25 μm, He, 2. K/min, 280. C @ 15. min; Tstart: 150. C
CapillaryDB-12133.Greinwald, Bachmann, et al., 1995He, 6. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 150. C; Tend: 300. C
CapillaryDB-12133.Greinwald, Henrichs, et al., 1995He, 6. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 150. C; Tend: 300. C
CapillaryDB-12132.Kirch, Veit, et al., 1995He, 6. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 150. C; Tend: 300. C
CapillaryDB-12127.van Wyk, Greinwald, et al., 19956. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 150. C; Tend: 300. C
CapillaryDB-12135.Greinwald, Canto, et al., 1992He, 6. K/min; Column length: 30. m; Column diameter: 0.32 mm; Tstart: 150. C; Tend: 300. C
CapillaryDB-12132.Wink and Witte, 199130. m/0.32 mm/1.0 μm, Helium, 150. C @ 1. min, 10. K/min; Tend: 300. C
CapillarySE-302130.Wink, Witte, et al., 1981He, 6. K/min; Column length: 15. m; Column diameter: 0.26 mm; Tstart: 150. C; Tend: 270. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-5 MS2104.Cook, Lee, et al., 2009Column length: 30. m; Column diameter: 0.25 mm; Program: 100 0C (1 min) 40 0C/min -> 200 0C 5 0C/min -> 275 0C (15 min)
CapillaryDB-12132.El-Shazly, Ateya, et al., 2001Helium; Column length: 15. m; Column diameter: 0.317 mm; Program: 150 0C (2 min) 15 0C/min -> 250 0C 25 0C/min -> 300 0C (5 min)
CapillaryOV-12132.Asres, Tei, et al., 1997He; Column length: 15. m; Column diameter: 0.25 mm; Program: 120C (2min) => 10C/min => 250C => 15C/min => 300C
CapillaryDB-12130.Greinwald, Ross, et al., 1996He; Column length: 15. m; Column diameter: 0.25 mm; Program: 150C(2min) => 10C/min => 250C => 20C/min => 300C (10min)
CapillaryDB-12130.Greinwald, van Rensen, et al., 1995He; Column length: 30. m; Column diameter: 0.32 mm; Program: 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min)
CapillaryDB-12130.Greinwald, Ross, et al., 1995He; Column length: 30. m; Column diameter: 0.32 mm; Program: 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min)
CapillaryDB-12132.Wink, Meissner, et al., 1995Column length: 30. m; Column diameter: 0.3 mm; Program: not specified
CapillaryDB-12130.Greinwald, Witte, et al., 1991He; Column length: 30. m; Column diameter: 0.32 mm; Program: 150C (2min) => 10C/min => 250C => 20C/min => 300C (5min)

References

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Beuerle, 2010
Beuerle, T., MS and RI data. Personal communication., 2010. [all data]

Martins, Wink, et al., 2005
Martins, A.; Wink, M.; Tei, A.; Brum-Bousquet, M.; Tillequin, F.; Rauter, A.-P., A phytochemical study of the quinolizidine alkaloids from Genista tenera by gas chromatography-mass spectrometry, Phytochem. Anal., 2005, 16, 4, 264-266, https://doi.org/10.1002/pca.832 . [all data]

Przybylak, Ciesiolka, et al., 2005
Przybylak, J.K.; Ciesiolka, D.; Wysocka, W.; García-López, P.M.; Ruiz-López, M.A.; Wysocki, W.; Gulewicz, K., Alkaloid profiles of Mexican wild lupin and an effect of alkaloid preparation from Lupinus exaltatus seeds on growth and yield of paprika (Capsicum annuum L.), Ind. Crops Prod., 2005, 21, 1, 1-7, https://doi.org/10.1016/j.indcrop.2003.12.001 . [all data]

Martínez-Herrera, Robledo-Quintos, et al., 2001
Martínez-Herrera, J.; Robledo-Quintos, N.; Mora-Escobedo, R.; Dávila-Ortiz, G., Alkaloid composition of Lupinus campestris from Mexico, J. Food Biochem., 2001, 25, 2, 117-125, https://doi.org/10.1111/j.1745-4514.2001.tb00728.x . [all data]

Greinwald, Bachmann, et al., 1995
Greinwald, R.; Bachmann, P.; Lewis, G.; Witte, L.; Czygan, F.-C., Alkaloids of the genus Poecilanthe (Leguminosae: Papilionoideae), Biochem. Syst. Ecol., 1995, 23, 5, 547-553, https://doi.org/10.1016/0305-1978(95)00050-5 . [all data]

Greinwald, Henrichs, et al., 1995
Greinwald, R.; Henrichs, C.; Veen, G.; Ross, J.H.; Witte, L.; Czygan, F.-C., A survey of alkaloids in templetonia biloba (Benth.) Polhill (Fabaceae: Brongniartieae), Biochem. Syst. Ecol., 1995, 23, 6, 649-654, https://doi.org/10.1016/0305-1978(95)00035-6 . [all data]

Kirch, Veit, et al., 1995
Kirch, J.; Veit, M.; Wätzig, Greinwald; Czygan, F.-C., Alkaloidal variation in Genista Iobelii s.l. (Fabaceae), Biochem. Syst. Ecol., 1995, 23, 6, 635-643, https://doi.org/10.1016/0305-1978(95)00037-2 . [all data]

van Wyk, Greinwald, et al., 1995
van Wyk, B.-E.; Greinwald, R.; Witte, L., Alkaloid variation in the Lupinus pusillus group (Fabaceae: tribe Genisteae), Biochem. Syst. Ecol., 1995, 23, 5, 533-537, https://doi.org/10.1016/0305-1978(95)00036-T . [all data]

Greinwald, Canto, et al., 1992
Greinwald, R.; Canto, P.; Bachmann, P.; Witte, L.; Czygan, F.-C., Distribution and taxdonomic significance of alkaloids in the Genista cinerea agregat, Biochem. Syst. Ecol., 1992, 20, 1, 75-81, https://doi.org/10.1016/0305-1978(92)90074-N . [all data]

Wink and Witte, 1991
Wink, M.; Witte, L., Storage of quinolizidine alkaloids in Macrosiphum albifrons and Aphis genistae (Homoptera: Aphididae), Entomol. Gener., 1991, 15, 4, 237-254, https://doi.org/10.1127/entom.gen/15/1991/237 . [all data]

Wink, Witte, et al., 1981
Wink, M.; Witte, L.; Hartmann. T., Quinolizidine Alkaloid Composition of Plants and of Photomixotrophis Cell Suspension Cultures of Sarothamnus scoparius and Orobanche rapum-genistae, Planta Medica, 1981, 43, 12, 342-352, https://doi.org/10.1055/s-2007-971522 . [all data]

Cook, Lee, et al., 2009
Cook, D.; Lee, S.T.; GArdner, D.R.; Pfister, J.A.; Welch, K.D.; Green, B.T.; Davis, T.Z.; Panter, K.E., The alkaloids profiles of lupinus sulphureus, J. Agric. Food Chem., 2009, 57, 4, 1646-1653, https://doi.org/10.1021/jf803468q . [all data]

El-Shazly, Ateya, et al., 2001
El-Shazly, A.; Ateya, A.-M.M.; Wink, M., Quinolizidine alkaloid profiles of lupunus varius orientalis. L. albus albus, L. hartwegii, and L. densiflorus, Z. Naturforsch., 2001, 56c, 21-30. [all data]

Asres, Tei, et al., 1997
Asres, K.; Tei, A.; Wink, M., Quinolizidine alkaloids from the East-African legume Dicraeopetalum stipulare harms, Biochem. Syst. Ecol., 1997, 25, 4, 305-308, https://doi.org/10.1016/S0305-1978(97)00004-5 . [all data]

Greinwald, Ross, et al., 1996
Greinwald, R.; Ross, J.H.; Witte, L.; Czygan, F.-C., Alkaloids of Templetonia incana, Biochem. Syst. Ecol., 1996, 24, 5, 423-426, https://doi.org/10.1016/0305-1978(96)00024-5 . [all data]

Greinwald, van Rensen, et al., 1995
Greinwald, R.; van Rensen, I.; Veit, M.; Canto, P.; Witte, L., A chemical dichotomy in quinolizidine alkaloid accumulation within the section Spartioides of the genus Genista (Fabaceae: Genisteae), Biochem. Syst. Ecol., 1995, 23, 1, 89-97, https://doi.org/10.1016/0305-1978(95)93662-M . [all data]

Greinwald, Ross, et al., 1995
Greinwald, R.; Ross, J.H.; Witte, L.; Czygan, F.-C., The alkaloid pattern of Plagiocarpus axillaris (Fabaceae: Brongniartieae), Biochem. Syst. Ecol., 1995, 23, 6, 645-648, https://doi.org/10.1016/0305-1978(95)00059-3 . [all data]

Wink, Meissner, et al., 1995
Wink, M.; Meissner, C.; Witte, L., Patterns of quinolizidine alkaloids in 56 species of the genus Lupinus, Phytochemistry, 1995, 38, 1, 139-153, https://doi.org/10.1016/0031-9422(95)91890-D . [all data]

Greinwald, Witte, et al., 1991
Greinwald, R.; Witte, L.; Wray, V.; Czygan, F.-C., The alkaloid pattern of Cytisophyllum sessilitolium (Fabaceae-Genisteae), Biochem. Syst. Ecol., 1991, 19, 3, 253-258, https://doi.org/10.1016/0305-1978(91)90010-W . [all data]


Notes

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