7-Methylenebicyclo[2.2.1]-heptane


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas60. ± 3.kJ/molCcbKozina, Bychikhina, et al., 1977 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-6975. ± 2.kJ/molCcbBelikova, Gazuko, et al., 1975Corresponding Δfliquid = 2112. kJ/mol (simple calculation by NIST; no Washburn corrections)
Quantity Value Units Method Reference Comment
Δfsolid20. ± 2.kJ/molCcbKozina, Bychikhina, et al., 1977 
Quantity Value Units Method Reference Comment
Δcsolid-4883. ± 2.kJ/molCcbKozina, Bychikhina, et al., 1977Corresponding Δfsolid = 20. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δsub41. ± 2.kJ/molVKozina, Bychikhina, et al., 1977ALS
Δsub40.0kJ/molN/AKozina, Bychikhina, et al., 1977DRB

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kozina, Bychikhina, et al., 1977
Kozina, M.P.; Bychikhina, L.V.; Gal'chenko, G.L., The enthalpies of combustion and formation of 2,2-dimethyl-3-methylene bicyclo[2,2,1]heptane and 7-methylenebicyclo[2,2,1]heptane, Russ. J. Phys. Chem. (Engl. Transl.), 1977, 51, 1258-1259. [all data]

Belikova, Gazuko, et al., 1975
Belikova, N.A.; Gazuko, I.V.; Ranneva, Yu.I.; Bychikhina, L.V.; Kozina, M.P.; Plate, A.F., The relative thermodynamic stabilities of unsaturated hydrocarbons of the bicyclo-[2.2.1]heptane and bicyclo[2.2.2]octane series, J. Org. Chem. USSR (Engl. Transl.), 1975, 10, 1689-1696. [all data]


Notes

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