Phosphoric acid, bis(trimethylsilyl) 2,3-bis[(trimethylsilyl)oxy]propyl ester

Formula: C₁₅H₄₁O₆PSi₄
Molecular weight: 460.7982
IUPAC Standard InChI: InChI=1S/C15H41O6PSi4/c1-23(2,3)18-14-15(19-24(4,5)6)13-17-22(16,20-25(7,8)9)21-26(10,11)12/h15H,13-14H2,1-12H3
IUPAC Standard InChIKey: OSNKBCBCOYHYNF-UHFFFAOYSA-N
CAS Registry Number: 31038-11-6
Chemical structure:
This structure is also available as a 2d Mol file
Other names: Phosphoric acid, 2,3-bis(trimethylsiloxy)propyl bis(trimethylsilyl) ester; 2,3-Bis[(trimethylsilyl)oxy]propyl bis(trimethylsilyl) phosphate; Glycerol-3-phosphate, 4TMS; .alpha.-Glycerophosphate, 4-O-TMS; α-Glycerophosphoric acid, tetrakis-TMS
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Other data available:
- Mass spectrum (electron ionization)
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Gas Chromatography

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Van Den Dool and Kratz RI, non-polar column, temperature ramp

Column type	Active phase	I	Reference	Comment
Capillary	DB-5	1744.	Fu, Iga, et al., 2000	30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min
Capillary	DB-5	1780.	Fu, Iga, et al., 2000	30. m/0.25 mm/0.25 μm, He, 100. C @ 1. min, 10. K/min, 290. C @ 8. min

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	HP-5	1797.	Isidorov, Lech, et al., 2008	30. m/0.25 mm/0.25 μm, Helium, 3. K/min, 300. C @ 30. min; T_start: 50. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type	Active phase	I	Reference	Comment
Capillary	Methylsiloxane, 5 % Ph groups	1787.	Cao, Aa, et al., 2011	Program: not specified
Capillary	RTx-5 Sil MS	1775.	Birkemeier and Kopka, 2007	30. m/0.25 mm/0.25 μm, Helium; Program: 70 0C (1 min) 1 0C/min -> 76 0C 6.09 0C/min -> 350 0C (1 min) -> 330 0C (10 min)

References

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Fu, Iga, et al., 2000
Fu, X.; Iga, M.; Kimura, M.; Yamaguchi, S., Simplified screening for organic acidemia using GC/MS and dried urine filter paper: a study on neonatal mass screening, Early Hum. Dev., 2000, 58, 1, 41-55, https://doi.org/10.1016/S0378-3782(00)00053-0 . [all data]

Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L., Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack, Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z . [all data]

Cao, Aa, et al., 2011
Cao, B.; Aa, J.; Wang, G.; Wu, X.; Liu, L.; Li, M.; Shi, J.; Wang, X.; Zhao, C.; Zheng, T.; Guo, S.; Duan, J., GC-TOFMS analysis of metabolites in adherent MDCK cells and a movel strategy for identifying intracellular metabolic markers for use as cell amount indicators in data normalization, Anal. Bioanal. Chem., 2011, 400, 9, 2983-2993, https://doi.org/10.1007/s00216-011-4981-8 . [all data]

Birkemeier and Kopka, 2007
Birkemeier, C.; Kopka, J., Design of metabolite recovery by variations of the metabolite profiling protocol in Concepts in Plant Metabolomics, Nikolau, B.J.; Wurtele, E.S., ed(s)., Springer, Dordrecht, Netheralnds, 2007, 45-69. [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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