titanium(4+) ethanolate


Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-1475.2 ± 5.2kJ/molReviewMartinho Simões 
Δfliquid-1463.9 ± 3.3kJ/molReviewMartinho Simões 
Δfliquid-1458.5 ± 5.3kJ/molReviewMartinho Simões 
Δfliquid-1461.2 ± 3.1kJ/molReviewMartinho SimõesSelected data. Average of the RSC results Bradley and Hillyer, 1966
Quantity Value Units Method Reference Comment
Δcliquid-5475.2 ± 5.0kJ/molCC-SBShaulov, Genchel, et al., 1972Please also see Pedley and Rylance, 1977 and Tel'noi and Rabinovich, 1977.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δvap100.4 ± 8.4kJ/molCC-SBBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

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Individual Reactions

4Ethanol (l) + Titanium tetrachloride (l) = titanium(4+) ethanolate (l) + 4(Hydrogen chloride • 51.3Water) (solution)

By formula: 4C2H6O (l) + Cl4Ti (l) = C8H20O4Ti (l) + 4(HCl • 51.3H2O) (solution)

Quantity Value Units Method Reference Comment
Δr-205.4 ± 4.2kJ/molRSCBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

4Ethanol (l) + Titanium tetrachloride (l) = titanium(4+) ethanolate (l) + 4Hydrogen chloride (g)

By formula: 4C2H6O (l) + Cl4Ti (l) = C8H20O4Ti (l) + 4HCl (g)

Quantity Value Units Method Reference Comment
Δr81.6 ± 0.4kJ/molRSCBradley and Hillyer, 1966Please also see Pedley and Rylance, 1977.

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Bradley and Hillyer, 1966
Bradley, D.C.; Hillyer, M.J., Trans. Faraday Soc., 1966, 62, 2367. [all data]

Shaulov, Genchel, et al., 1972
Shaulov, Yu.Kh.; Genchel, V.G.; Aizatullova, R.M.; Petrova, N.V., Zh. Fiz. Khim., 1972, 46, 2382. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B., Russ. Chem. Rev., 1977, 46, 689. [all data]


Notes

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