Diamantan-3-ol

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-71.1 ± 1.1kcal/molCcbClark, Knox, et al., 1980 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-98.89 ± 0.35kcal/molCcbClark, Knox, et al., 1980 
Quantity Value Units Method Reference Comment
Δcsolid-1900.97 ± 0.35kcal/molCcbClark, Knox, et al., 1980Corresponding Δfsolid = -98.90 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub27.8 ± 1.0kcal/molCClark, Knox, et al., 1980ALS
Δsub27.77kcal/molN/AClark, Knox, et al., 1980DRB

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Reference Comment
27.7 ± 1.1338.Clark, Knox, et al., 1980, 2Based on data from 323. to 354. K. See also Clark, Knox, et al., 1975.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clark, Knox, et al., 1980
Clark, T.; Knox, T.M.; McKervey, M.A.; Mackle, H., Thermochemistry of bridged-ring substances. Enthalpies of formation of diamantan-1-, -3-, and -4-ol and of diamantanone, J. Chem. Soc. Perkin Trans. 2, 1980, 1686-1689. [all data]

Clark, Knox, et al., 1980, 2
Clark, Timothy; Knox, McO.; McKervey, M. Anthony; Mackle, Henry, Thermochemistry of bridged-ring substances. Enthalpies of formation of diamantan-1-, -3-, and -4-ol and of diamantanone, J. Chem. Soc., Perkin Trans. 2, 1980, 11, 1686, https://doi.org/10.1039/p29800001686 . [all data]

Clark, Knox, et al., 1975
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J., Heats of sublimation of some cage hydrocarbons by a temperature scanning technique, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107 . [all data]


Notes

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