Diamantan-1-ol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-428.8 ± 1.0kJ/molCcbClark, Knox, et al., 1980 
Quantity Value Units Method Reference Comment
Δcsolid-7938.6 ± 1.0kJ/molCcbClark, Knox, et al., 1980Corresponding Δfsolid = -428.82 kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δsub117.9kJ/molN/AClark, Knox, et al., 1980DRB

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
118. ± 0.6334.N/AClark, Knox, et al., 1980, 2Based on data from 319. to 349. K. See also Clark, Knox, et al., 1975.; AC
117.9 ± 0.59334.CClark, Knox, et al., 1980ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
9.6573.DSCClark, McKervey, et al., 1974AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Clark, Knox, et al., 1980
Clark, T.; Knox, T.M.; McKervey, M.A.; Mackle, H., Thermochemistry of bridged-ring substances. Enthalpies of formation of diamantan-1-, -3-, and -4-ol and of diamantanone, J. Chem. Soc. Perkin Trans. 2, 1980, 1686-1689. [all data]

Clark, Knox, et al., 1980, 2
Clark, Timothy; Knox, McO.; McKervey, M. Anthony; Mackle, Henry, Thermochemistry of bridged-ring substances. Enthalpies of formation of diamantan-1-, -3-, and -4-ol and of diamantanone, J. Chem. Soc., Perkin Trans. 2, 1980, 11, 1686, https://doi.org/10.1039/p29800001686 . [all data]

Clark, Knox, et al., 1975
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J., Heats of sublimation of some cage hydrocarbons by a temperature scanning technique, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107 . [all data]

Clark, McKervey, et al., 1974
Clark, Timothy; McKervey, M. Anthony; Mackle, Henry; Rooney, John J., Pre-melting transitions in caged hydrocarbons, a general theory of disorder in plastic crystals, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 0, 1279, https://doi.org/10.1039/f19747001279 . [all data]


Notes

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