Carbon monosulfide


Gas phase thermochemistry data

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas67.000kcal/molReviewChase, 1998Data last reviewed in December, 1976
Quantity Value Units Method Reference Comment
gas,1 bar50.323cal/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. to 600.600. to 6000.
A 5.2016908.240251
B 5.9748810.708952
C -1.934891-0.227228
D -1.0908100.027179
E 0.030204-0.238404
F 65.3042163.82110
G 55.1027059.05189
H 67.0001067.00010
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Iron ion (1+) + Carbon monosulfide = (Iron ion (1+) • Carbon monosulfide)

By formula: Fe+ + CS = (Fe+ • CS)

Quantity Value Units Method Reference Comment
Δr49.5 ± 3.1kcal/molCIDTRodgers and Armentrout, 2000 
Δr55.2 ± 2.8kcal/molCIDTSchroeder, Kretzschmar, et al., 1999 

Cobalt ion (1+) + Carbon monosulfide = (Cobalt ion (1+) • Carbon monosulfide)

By formula: Co+ + CS = (Co+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 7.8kcal/molCIDTRue, Armentrout, et al., 2001 
Δr57.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Chromium ion (1+) + Carbon monosulfide = (Chromium ion (1+) • Carbon monosulfide)

By formula: Cr+ + CS = (Cr+ • CS)

Quantity Value Units Method Reference Comment
Δr38.9 ± 1.4kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr37.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Manganese ion (1+) + Carbon monosulfide = (Manganese ion (1+) • Carbon monosulfide)

By formula: Mn+ + CS = (Mn+ • CS)

Quantity Value Units Method Reference Comment
Δr19.1 ± 5.1kcal/molCIDTRue, Armentrout, et al., 2001, 2 
Δr18.6 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Molybdenum ion (1+) + Carbon monosulfide = (Molybdenum ion (1+) • Carbon monosulfide)

By formula: Mo+ + CS = (Mo+ • CS)

Quantity Value Units Method Reference Comment
Δr38.7 ± 3.2kcal/molCIDTSchroeder, Kretzschmar, et al., 2003 
Δr38.7 ± 4.3kcal/molCIDTRodgers and Armentrout, 2000 

Titanium ion (1+) + Carbon monosulfide = (Titanium ion (1+) • Carbon monosulfide)

By formula: Ti+ + CS = (Ti+ • CS)

Quantity Value Units Method Reference Comment
Δr36.8 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000 

Scandium ion (1+) + Carbon monosulfide = (Scandium ion (1+) • Carbon monosulfide)

By formula: Sc+ + CS = (Sc+ • CS)

Quantity Value Units Method Reference Comment
Δr31.8 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Zirconium ion (1+) + Carbon monosulfide = (Zirconium ion (1+) • Carbon monosulfide)

By formula: Zr+ + CS = (Zr+ • CS)

Quantity Value Units Method Reference Comment
Δr61.7 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Silver ion (1+) + Carbon monosulfide = (Silver ion (1+) • Carbon monosulfide)

By formula: Ag+ + CS = (Ag+ • CS)

Quantity Value Units Method Reference Comment
Δr36.3 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Vanadium ion (1+) + Carbon monosulfide = (Vanadium ion (1+) • Carbon monosulfide)

By formula: V+ + CS = (V+ • CS)

Quantity Value Units Method Reference Comment
Δr39.2 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Yttrium ion (1+) + Carbon monosulfide = (Yttrium ion (1+) • Carbon monosulfide)

By formula: Y+ + CS = (Y+ • CS)

Quantity Value Units Method Reference Comment
Δr32.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000 

Nickel ion (1+) + Carbon monosulfide = (Nickel ion (1+) • Carbon monosulfide)

By formula: Ni+ + CS = (Ni+ • CS)

Quantity Value Units Method Reference Comment
Δr56.4 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Zinc ion (1+) + Carbon monosulfide = (Zinc ion (1+) • Carbon monosulfide)

By formula: Zn+ + CS = (Zn+ • CS)

Quantity Value Units Method Reference Comment
Δr33.7 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000 

Copper ion (1+) + Carbon monosulfide = (Copper ion (1+) • Carbon monosulfide)

By formula: Cu+ + CS = (Cu+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000 

Niobium ion (1+) + Carbon monosulfide = (Niobium ion (1+) • Carbon monosulfide)

By formula: Nb+ + CS = (Nb+ • CS)

Quantity Value Units Method Reference Comment
Δr57.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000 

Ruthenium ion (1+) + Carbon monosulfide = (Ruthenium ion (1+) • Carbon monosulfide)

By formula: Ru+ + CS = (Ru+ • CS)

Quantity Value Units Method Reference Comment
Δr60.5 ± 4.8kcal/molCIDTRodgers and Armentrout, 2000 

Palladium ion (1+) + Carbon monosulfide = (Palladium ion (1+) • Carbon monosulfide)

By formula: Pd+ + CS = (Pd+ • CS)

Quantity Value Units Method Reference Comment
Δr47.8 ± 3.3kcal/molCIDTRodgers and Armentrout, 2000 

Rh+ + Carbon monosulfide = (Rh+ • Carbon monosulfide)

By formula: Rh+ + CS = (Rh+ • CS)

Quantity Value Units Method Reference Comment
Δr55.9 ± 4.5kcal/molCIDTRodgers and Armentrout, 2000 

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Schroeder, Kretzschmar, et al., 1999
Schroeder, D.; Kretzschmar, I.; Schwarz; Rue, C.; Armentrout, P.B., On the Structural Dichotomy of Cationic, Anionic, and Neutral FeS2, Inorg. Chem., 1999, 38, 15, 3474, https://doi.org/10.1021/ic990241b . [all data]

Rue, Armentrout, et al., 2001
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of Fe+ and Co+ With CS2 and COS, J. Phys. Chem. A, 2001, 105, 37, 8456, https://doi.org/10.1021/jp0120716 . [all data]

Rue, Armentrout, et al., 2001, 2
Rue, C.; Armentrout, P.B.; Kretzschmar, I.; Schroeder, D.; Schwarz, H., Guided Ion Beam Studies of the Reactions of the State-Specific Reactions of Cr+ and Mn+ with CS2 and COS, Int. J. Mass Spectrom., 2001, 210/211, 283, https://doi.org/10.1016/S1387-3806(01)00400-6 . [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References