Cyclodecane

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-6586.2 ± 0.9kJ/molCcbCoops, Van Kamp, et al., 1960Corresponding Δfliquid = -207.2 kJ/mol (simple calculation by NIST; no Washburn corrections)
Δcliquid-6600.3 ± 6.3kJ/molCcbHuckel, Gercke, et al., 1933Corresponding Δfliquid = -193.1 kJ/mol (simple calculation by NIST; no Washburn corrections)

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + Cyclodecyne = Cyclodecane

By formula: 2H2 + C10H16 = C10H20

Quantity Value Units Method Reference Comment
Δr-236.2 ± 0.96kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid
Δr-236.kJ/molChydSicher, Svoboda, et al., 1966liquid phase; solvent: Acetic acid

2Hydrogen + trans,trans-1,6-Cyclodecadiene = Cyclodecane

By formula: 2H2 + C10H16 = C10H20

Quantity Value Units Method Reference Comment
Δr-199.3kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

cis,cis-1,6-Cyclodecadiene + 2Hydrogen = Cyclodecane

By formula: C10H16 + 2H2 = C10H20

Quantity Value Units Method Reference Comment
Δr-183.0kJ/molChydTurner, Mallon, et al., 1973liquid phase; solvent: Glacial acetic acid

Hydrogen + Cyclodecene, (Z)- = Cyclodecane

By formula: H2 + C10H18 = C10H20

Quantity Value Units Method Reference Comment
Δr-86.5 ± 0.3kJ/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid

Hydrogen + Cyclodecene, (E)- = Cyclodecane

By formula: H2 + C10H18 = C10H20

Quantity Value Units Method Reference Comment
Δr-100. ± 4.kJ/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid

4Hydrogen + Meso 1,2,6,7-cyclodecatetraene = Cyclodecane

By formula: 4H2 + C10H12 = C10H20

Quantity Value Units Method Reference Comment
Δr-514.6 ± 0.8kJ/molChydRoth, Adamczak, et al., 1991liquid phase

References

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Coops, Van Kamp, et al., 1960
Coops, J.; Van Kamp, H.; Lambregts, W.A.; Visser, B.J.; Dekker, H., Thermal quantities of cycloparaffins. Part IV. Heats of combustion of cycloparaffins with 10-17 C atoms, Rec. Trav. Chim. Pays/Bas, 1960, 79, 1226-1234. [all data]

Huckel, Gercke, et al., 1933
Huckel, W.; Gercke, A.; Gross, A., Cyclodecan, Ber., 1933, 66, 563-567. [all data]

Turner, Jarrett, et al., 1973
Turner, R.B.; Jarrett, A.D.; Goebel, P.; Mallon, B.J., Heats of hydrogenation. 9. Cyclic acetylenes and some miscellaneous olefins, J. Am. Chem. Soc., 1973, 95, 790-792. [all data]

Sicher, Svoboda, et al., 1966
Sicher, J.; Svoboda, M.; Zavada, J.; Turner, R.B.; Goebel, P., Sterochemical studies - XXXVI. An approach to conformational analysis of medium ring compounds. Unsaturated ten-membered ring derivates, Tetrahedron, 1966, 22, 659-671. [all data]

Turner, Mallon, et al., 1973
Turner, R.B.; Mallon, B.J.; Tichy, M.; Doering, W.v.E.; Roth, W.R.; Schroder, G., Heats of hydrogenation. X. Conjugative interaction in cyclic dienes and trienes, J. Am. Chem. Soc., 1973, 95, 8605-8610. [all data]

Turner and Meador, 1957
Turner, R.B.; Meador, W.R., Heats of hydrogenation. IV. Hydrogenation of some cis- and trans-cycloolefins, J. Am. Chem. Soc., 1957, 79, 4133-4136. [all data]

Roth, Adamczak, et al., 1991
Roth, W.R.; Adamczak, O.; Breuckmann, R.; Lennartz, H.-W.; Boese, R., Die Berechnung von Resonanzenergien; das MM2ERW-Kraftfeld, Chem. Ber., 1991, 124, 2499-2521. [all data]


Notes

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