Benzene, 1-chloro-3-isocyanato-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δcliquid-3277. ± 64.kJ/molCcbZalikin, Kochetkov, et al., 1965ALS
Quantity Value Units Method Reference Comment
Δfsolid-82.8 ± 4.2kJ/molCcbSelivanov and Konstantinov, 1975ALS
Quantity Value Units Method Reference Comment
Δcsolid-3264. ± 4.2kJ/molCcbSelivanov and Konstantinov, 1975ALS

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
187.0294.2Zalikin, Kochetkov, et al., 1965T = 294, 323 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap54.0 ± 0.2kJ/molVZalikin, Kochetkov, et al., 1965ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
53.1359.AStephenson and Malanowski, 1987Based on data from 344. to 432. K. See also Goldberg, Gorbushchenkov, et al., 1964.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
303. to 388.2.862341067.251-126.851Zalikin, Kochetkov, et al., 1965Coefficents calculated by NIST from author's data.
344. to 431.53.599061325.111-111.257Goldberg, Gorbushchenkov, et al., 1964, 2Coefficents calculated by NIST from author's data.

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Zalikin, Kochetkov, et al., 1965
Zalikin, A.A.; Kochetkov, V.L.; Strepikheev, Yu.A., Some physical and physicochemical constants of m- and p-chloroaniline and of m- and p-chlorophenyl isocyanate, Khim. Prom. (Moscow), 1965, 41, 338. [all data]

Selivanov and Konstantinov, 1975
Selivanov, V.D.; Konstantinov, I.I., Thermochemistry of chloroaryl isocyanates, Russ. J. Phys. Chem. (Engl. Transl.), 1975, 49, 620-621. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Goldberg, Gorbushchenkov, et al., 1964
Goldberg, N.A.; Gorbushchenkov, V.A.; Teplova, Z.G., Zh. Prikl. Khim. (S.-Peterburg), 1964, 37, 745. [all data]

Goldberg, Gorbushchenkov, et al., 1964, 2
Goldberg, N.A.; Gorbushchenkov, V.A.; Teplova, Z.G., Some Physical Property of m-Chlorphenyl Isocyonate, Zh. Prikl. Khim. (Leningrad), 1964, 37, 745-747. [all data]


Notes

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