CH2=N anion


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

CH2N- + Hydrogen cation = Methanimine

By formula: CH2N- + H+ = CH3N

Quantity Value Units Method Reference Comment
Δr1625. ± 21.kJ/molG+TSKass and DePuy, 1985gas phase
Quantity Value Units Method Reference Comment
Δr1594. ± 21.kJ/molIMRBKass and DePuy, 1985gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Protonation reactions

CH2N- + Hydrogen cation = Methanimine

By formula: CH2N- + H+ = CH3N

Quantity Value Units Method Reference Comment
Δr1625. ± 21.kJ/molG+TSKass and DePuy, 1985gas phase
Quantity Value Units Method Reference Comment
Δr1594. ± 21.kJ/molIMRBKass and DePuy, 1985gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kass and DePuy, 1985
Kass, S.R.; DePuy, C.H., Gas phase ion chemistry of azides. The generation of CH=N- and CH2=NCH2-, J. Org. Chem., 1985, 50, 2874. [all data]


Notes

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