1H-1,2,4-Triazole

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Δfgas46.1 ± 0.2kcal/molCcbJimenez, Roux, et al., 1989ALS
Δfgas46.30 ± 0.45kcal/molCcbFaour and Akasheh, 1985ALS
Δfgas45.05kcal/molN/AMasalitinova, Oleinikova, et al., 1984Value computed using ΔfHsolid° value of 107.9±0.5 kj/mol from Masalitinova, Oleinikova, et al., 1984 and ΔsubH° value of 80.6 kj/mol from Jimenez, Roux, et al., 1989.; DRB
Δfgas45.36kcal/molN/AAleksandrov, Osipova, et al., 1982Value computed using ΔfHsolid° value of 109.2±0.9 kj/mol from Aleksandrov, Osipova, et al., 1982 and ΔsubH° value of 80.6 kj/mol from Jimenez, Roux, et al., 1989.; DRB

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid25.98 ± 0.1kcal/molCcbJimenez, Roux, et al., 1989ALS
Δfsolid27.03 ± 0.33kcal/molCcbFaour and Akasheh, 1985ALS
Δfsolid25.79 ± 0.11kcal/molCcbMasalitinova, Oleinikova, et al., 1984ALS
Δfsolid26.10 ± 0.22kcal/molCcbAleksandrov, Osipova, et al., 1982ALS
Quantity Value Units Method Reference Comment
Δcsolid-316.54 ± 0.07kcal/molCcbJimenez, Roux, et al., 1989ALS
Δcsolid-317.61 ± 0.29kcal/molCcbFaour and Akasheh, 1985ALS
Δcsolid-316.362 ± 0.088kcal/molCcbMasalitinova, Oleinikova, et al., 1984ALS
Δcsolid-316.68 ± 0.22kcal/molCcbAleksandrov, Osipova, et al., 1982ALS
Δcsolid-316.8kcal/molCcbZimmerman and Geisenfelder, 1961ALS

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
18.8298.15Jimenez, Roux, et al., 1989DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil533.2KN/AAldrich Chemical Company Inc., 1990BS
Tboil477.15KN/ABruhl, 1895Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Tfus393.5KN/AHilgeman, Mouroux, et al., 1989Uncertainty assigned by TRC = 0.4 K; TRC
Tfus392.KN/AVorontsova and Vlasov, 1987Crystal phase 1 phase; Uncertainty assigned by TRC = 0.5 K; TRC
Tfus295.15KN/ABruhl, 1895Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Δsub19.8 ± 0.7kcal/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
3.8480393.5Hilgeman, Mouroux, et al., 1989, 2DH
2.57 ± 0.02393.3Sabbah and Perez, 1999AC
3.85393.5Domalski and Hearing, 1996AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C2H2N3- + Hydrogen cation = 1H-1,2,4-Triazole

By formula: C2H2N3- + H+ = C2H3N3

Quantity Value Units Method Reference Comment
Δr344.2 ± 2.1kcal/molG+TSTaft, 1991gas phase; B
Quantity Value Units Method Reference Comment
Δr336.9 ± 2.0kcal/molIMRETaft, 1991gas phase; B

Sodium ion (1+) + 1H-1,2,4-Triazole = (Sodium ion (1+) • 1H-1,2,4-Triazole)

By formula: Na+ + C2H3N3 = (Na+ • C2H3N3)

Quantity Value Units Method Reference Comment
Δr29.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
0.00.CIDTRodgers and Armentrout, 2000RCD

1-[1,2,4]Triazol-1-ylethanone + Water = 1H-1,2,4-Triazole + Acetic acid

By formula: C4H5N3O + H2O = C2H3N3 + C2H4O2

Quantity Value Units Method Reference Comment
Δr-7.29 ± 0.06kcal/molCmWadso, 1960solid phase; Heat of hydrolysis; ALS

1-Butanamine + 1-[1,2,4]Triazol-1-ylethanone = Acetamide, N-butyl- + 1H-1,2,4-Triazole

By formula: C4H11N + C4H5N3O = C6H13NO + C2H3N3

Quantity Value Units Method Reference Comment
Δr-20.50 ± 0.06kcal/molCmWadso, 1962solid phase; ALS

1H-1,2,3-Triazole = 1H-1,2,4-Triazole

By formula: C2H3N3 = C2H3N3

Quantity Value Units Method Reference Comment
Δr2.8kcal/molEqkMauret, Fayet, et al., 1973liquid phase; solvent: Benzene; ALS

1-[1,2,4]Triazol-1-ylethanone + Aniline = Acetamide, N-phenyl- + 1H-1,2,4-Triazole

By formula: C4H5N3O + C6H7N = C8H9NO + C2H3N3

Quantity Value Units Method Reference Comment
Δr-17.28 ± 0.08kcal/molCmWadso, 1962solid phase; ALS

Lithium ion (1+) + 1H-1,2,4-Triazole = (Lithium ion (1+) • 1H-1,2,4-Triazole)

By formula: Li+ + C2H3N3 = (Li+ • C2H3N3)

Quantity Value Units Method Reference Comment
Δr45.7 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Potassium ion (1+) + 1H-1,2,4-Triazole = (Potassium ion (1+) • 1H-1,2,4-Triazole)

By formula: K+ + C2H3N3 = (K+ • C2H3N3)

Quantity Value Units Method Reference Comment
Δr20.8 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jimenez, Roux, et al., 1989
Jimenez, P.; Roux, M.V.; Turrion, C., Thermochemical properties of N-heterocyclic compounds II. Enthalpies of combustion, vapour pressures, enthalpies of sublimation, and enthalpies of formation of 1,2,4-triazole and benzotriazole, J. Chem. Thermodyn., 1989, 21, 759-764. [all data]

Faour and Akasheh, 1985
Faour, M.; Akasheh, T.S., Heat of combustion of some N-heterocycle compounds. Part 1, J. Chem. Soc. Perkin Trans. 2, 1985, 811-713. [all data]

Masalitinova, Oleinikova, et al., 1984
Masalitinova, T.N.; Oleinikova, T.P.; Polyakova, L.P., Thermochemical study of 1,2,4-triazole as a reference substnace for the calorimetry of combustion of organonitrogen compounds, Ref. Zh., Khim.; Abstr. No. 7B3028, 1984, 0. [all data]

Aleksandrov, Osipova, et al., 1982
Aleksandrov, Yu.I.; Osipova, T.R.; Yuhkevich, V.F., Study of 1,2,4-triazole as a standard sample in the calorimetry of thoroughly nitrided organic compounds, Termodin. Organ. Soedin., 1982, 42-45. [all data]

Zimmerman and Geisenfelder, 1961
Zimmerman, H.; Geisenfelder, H., Uber die Mesomerieenergie von Azolen, Z. Electrochem., 1961, 65, 368-371. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Bruhl, 1895
Bruhl, J.W., Spectrochemistry of Nitrogen-Containing Compounds. I., Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1895, 16, 193. [all data]

Hilgeman, Mouroux, et al., 1989
Hilgeman, F.R.; Mouroux, F.Y.N.; Mok, D.; Holan, M.K., Phase Diagrams of Binary Solid Azole Systems, J. Chem. Eng. Data, 1989, 34, 220. [all data]

Vorontsova and Vlasov, 1987
Vorontsova, N.A.; Vlasov, O.N., Determination of saturated vapor pressure of Bayletone and its semiproducts, Deposited Doc. ONIITEkhim Cherkassy, 1987, Doc. No. 1423 khp - 87, 1987. [all data]

Hilgeman, Mouroux, et al., 1989, 2
Hilgeman, F.R.; Mouroux, F.Y.N.; Mok, D.; Holan, M.K., Phase diagrams of binary solid azole systems, J. Chem. Eng. Data, 1989, 34, 220-222. [all data]

Sabbah and Perez, 1999
Sabbah, Raphaël; Perez, Laurence, Energetics of Intramolecular Bonds in 1H-1,2,4-Triazole and 1H-Benzotriazole, Aust. J. Chem., 1999, 52, 4, 235-621, https://doi.org/10.1071/C99006 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Taft, 1991
Taft, R.W., , personal communication, Aug, 1991. [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Wadso, 1960
Wadso, I., Heats of hydrolysis of N-acetylated imidazole, 1,2,4-triazole and tetrazole, Acta Chem. Scand., 1960, 14, 903-908. [all data]

Wadso, 1962
Wadso, I., Heats of aminolysis and hydrolysis of some N-acetyl compounds and of acetic anhydride, Acta Chem. Scand., 1962, 16, 471-478. [all data]

Mauret, Fayet, et al., 1973
Mauret, P.; Fayet, J.P.; Fabre, M.; Elguero, J.; Pardo, M.d.C., Tautomerism study of υ-triazole from dipolar moment measurements, J. Chim. Phys. Phys.-Chim. Biol., 1973, 70, 1483-1485. [all data]


Notes

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