Cyclopentane

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Gas phase thermochemistry data

Go To: Top, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-76.40 ± 0.79kJ/molCcbMcCullough, Pennington, et al., 1959ALS
Δfgas-76.9kJ/molN/ASpitzer and Huffman, 1947Value computed using ΔfHliquid° value of -105.6±1.8 kj/mol from Spitzer and Huffman, 1947 and ΔvapH° value of 28.7 kj/mol from Prosen, Johnson, et al., 1946.; DRB
Δfgas-77.24 ± 0.75kJ/molCcbProsen, Johnson, et al., 1946ALS

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
37.5850.Dorofeeva O.V., 1986Recommended values are in good agreement with those calculated by [ Kilpatrick J.E., 1947, McCullough J.P., 1959] at low temperatures. The discrepancies increase at higher temperatures and amount to 1.8 J/mol*K for S(1500 K) and 2.1 J/mol*K for Cp(1500 K) obtained by [ McCullough J.P., 1959]. Calculation [ Sundaram S., 1963] seems to be incorrect because discrepancies with these data reach 23 and 7 J/mol*K for S(T) and Cp(T), respectively.; GT
40.18100.
45.30150.
54.19200.
74.48273.15
82.8 ± 2.0298.15
83.39300.
118.15400.
150.05500.
177.07600.
199.70700.
218.80800.
235.02900.
248.881000.
260.761100.
270.961200.
279.751300.
287.341400.
293.921500.

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
93.96 ± 0.19329.05McCullough J.P., 1959Please also see Spitzer R., 1946.; GT
102.01 ± 0.84353.
108.16 ± 0.84372.
117.3 ± 1.3395.
117.09 ± 0.23395.05
126.3 ± 1.3424.
138.7 ± 1.3463.
139.47 ± 0.28463.10
150.7 ± 1.7503.
160.1 ± 1.7539.

Phase change data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil322.4 ± 0.3KAVGN/AAverage of 34 out of 39 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus179.2 ± 0.8KAVGN/AAverage of 26 out of 27 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple179.71KN/ADouslin and Huffman, 1946Crystal phase 1 phase; Uncertainty assigned by TRC = 0.05 K; To = 273.16 K; TRC
Ttriple179.71KN/ADouslin and Huffman, 1946Crystal phase 1 phase; Uncertainty assigned by TRC = 0.007 K; To = 273.16 K; TRC
Ttriple179.69KN/AAston, Finke, et al., 1943Uncertainty assigned by TRC = 0.08 K; TRC
Ttriple179.0KN/AJacobs and Parks, 1934Crystal phase 1 phase; Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc511.7 ± 0.2KN/ADaubert, 1996 
Tc511.6KN/AMajer and Svoboda, 1985 
Tc511.7KN/AKudchadker, Alani, et al., 1968Uncertainty assigned by TRC = 0.2 K; TRC
Tc511.6KN/AAmbrose and Grant, 1957Uncertainty assigned by TRC = 0.15 K; TRC
Tc511.75KN/AKay, 1947Uncertainty assigned by TRC = 0.05 K; TRC
Quantity Value Units Method Reference Comment
Pc45.1 ± 0.4barN/ADaubert, 1996 
Pc45.08barN/AKudchadker, Alani, et al., 1968Uncertainty assigned by TRC = 0.4053 bar; TRC
Pc44.30barN/AAmbrose and Grant, 1957Uncertainty assigned by TRC = 0.5066 bar; TRC
Pc45.1403barN/AKay, 1947Uncertainty assigned by TRC = 0.0506 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.259l/molN/ADaubert, 1996 
Quantity Value Units Method Reference Comment
ρc3.85 ± 0.04mol/lN/ADaubert, 1996 
ρc3.850mol/lN/AKudchadker, Alani, et al., 1968Uncertainty assigned by TRC = 0.06 mol/l; TRC
ρc3.85mol/lN/AKay, 1947Uncertainty assigned by TRC = 0.03 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap28.8 ± 0.6kJ/molAVGN/AAverage of 8 values; Individual data points

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
27.3322.4N/AMajer and Svoboda, 1985 
29.213298.15N/AAston, Fink, et al., 1943P = 41.10 kPa; DH
29.2295.AStephenson and Malanowski, 1987Based on data from 280. to 331. K.; AC
28.0337.AStephenson and Malanowski, 1987Based on data from 322. to 384. K.; AC
27.2396.AStephenson and Malanowski, 1987Based on data from 381. to 455. K.; AC
27.5467.AStephenson and Malanowski, 1987Based on data from 452. to 511. K.; AC
27.9 ± 0.1310.CMcCullough, Pennington, et al., 1959AC
27.3 ± 0.1322.CMcCullough, Pennington, et al., 1959AC
27.4323.N/ASpitzer and Pitzer, 1946AC
29.0304.MMWillingham, Taylor, et al., 1945Based on data from 289. to 323. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) β Tc (K) Reference Comment
298. to 323.41.640.2597511.6Majer and Svoboda, 1985 

Entropy of vaporization

ΔvapS (J/mol*K) Temperature (K) Reference Comment
97.98298.15Aston, Fink, et al., 1943P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
288.86 to 323.184.002881119.208-42.412Williamham, Taylor, et al., 1945 
225.90 to 287.394.247141235.305-30.666Aston, Fink, et al., 1943Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
42.6122.BBondi, 1963AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Reference Comment
0.6179.7Domalski and Hearing, 1996AC

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
5.195121.95crystaline, IIIcrystaline, IIRahm and Gmelin, 1992DH
0.361138.22crystaline, IIcrystaline, IRahm and Gmelin, 1992DH
0.615179.21crystaline, IliquidRahm and Gmelin, 1992DH
4.8844122.36crystaline, IIIcrystaline, IISzasz, Morrison, et al., 1947DH
0.3427138.07crystaline, IIcrystaline, ISzasz, Morrison, et al., 1947Temperature from 43AST/FIN.; DH
0.6038179.69crystaline, IliquidSzasz, Morrison, et al., 1947Temperature from 43AST/FIN.; DH
4.8840122.39crystaline, IIIcrystaline, IIDouslin and Huffman, 1946, 2DH
0.34443138.09crystaline, IIcrystaline, IDouslin and Huffman, 1946, 2DH
0.60894179.71crystaline, IliquidDouslin and Huffman, 1946, 2DH
4.874122.39crystaline, IIIcrystaline, IIAston, Fink, et al., 1943DH
0.3464138.07crystaline, IIcrystaline, IAston, Fink, et al., 1943DH
0.602179.69crystaline, IliquidAston, Fink, et al., 1943DH
4.745121.6crystaline, IIIcrystaline, IIJacobs and Parks, 1934, 2DH
0.3582137.1crystaline, IIcrystaline, IJacobs and Parks, 1934, 2DH
0.6046179.0crystaline, IliquidJacobs and Parks, 1934, 2DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
39.92122.36crystaline, IIIcrystaline, IISzasz, Morrison, et al., 1947DH
2.48138.07crystaline, IIcrystaline, ISzasz, Morrison, et al., 1947Temperature; DH
3.36179.69crystaline, IliquidSzasz, Morrison, et al., 1947Temperature; DH
39.91122.39crystaline, IIIcrystaline, IIDouslin and Huffman, 1946, 2DH
2.49138.09crystaline, IIcrystaline, IDouslin and Huffman, 1946, 2DH
3.38179.71crystaline, IliquidDouslin and Huffman, 1946, 2DH
39.82122.39crystaline, IIIcrystaline, IIAston, Fink, et al., 1943DH
2.51138.07crystaline, IIcrystaline, IAston, Fink, et al., 1943DH
3.35179.69crystaline, IliquidAston, Fink, et al., 1943DH
39.02121.6crystaline, IIIcrystaline, IIJacobs and Parks, 1934, 2DH
2.61137.1crystaline, IIcrystaline, IJacobs and Parks, 1934, 2DH
3.38179.0crystaline, IliquidJacobs and Parks, 1934, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + Cyclopentene = Cyclopentane

By formula: H2 + C5H8 = C5H10

Quantity Value Units Method Reference Comment
Δr-112.7 ± 0.54kJ/molChydAllinger, Dodziuk, et al., 1982liquid phase; solvent: Hexane; ALS
Δr-112. ± 0.8kJ/molChydRoth and Lennartz, 1980liquid phase; solvent: Cyclohexane; ALS
Δr-109.0 ± 1.8kJ/molChydTurner, Jarrett, et al., 1973liquid phase; solvent: Acetic acid; ALS
Δr-110. ± 0.8kJ/molChydRogers and McLafferty, 1971liquid phase; solvent: Hydrocarbon; ALS
Δr-111.6 ± 0.3kJ/molChydDolliver, Gresham, et al., 1937gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -112.6 ± 0.3 kJ/mol; At 355 °K; ALS

C5H9- + Hydrogen cation = Cyclopentane

By formula: C5H9- + H+ = C5H10

Quantity Value Units Method Reference Comment
Δr1741. ± 8.4kJ/molBranDePuy, Gronert, et al., 1989gas phase; B
Δr1750. ± 8.4kJ/molBranPeerboom, Rademaker, et al., 1992gas phase; B
Quantity Value Units Method Reference Comment
Δr1705. ± 8.8kJ/molH-TSDePuy, Gronert, et al., 1989gas phase; B
Δr1714. ± 8.8kJ/molH-TSPeerboom, Rademaker, et al., 1992gas phase; B

Hydrogen + Bicyclo[2.1.0]pentane = Cyclopentane

By formula: H2 + C5H8 = C5H10

Quantity Value Units Method Reference Comment
Δr-235. ± 0.4kJ/molChydRoth, Klarner, et al., 1980liquid phase; solvent: Heptane; ALS
Δr-230.7 ± 1.5kJ/molChydTurner, Goebel, et al., 1968liquid phase; solvent: Acetic acid; ALS

2Hydrogen + 1,3-Cyclopentadiene = Cyclopentane

By formula: 2H2 + C5H6 = C5H10

Quantity Value Units Method Reference Comment
Δr-210.8 ± 0.84kJ/molChydKistiakowsky, Ruhoff, et al., 1936gas phase; Reanalyzed by Cox and Pilcher, 1970, Original value = -212.8 ± 0.84 kJ/mol; At 355 °K; ALS

2Hydrogen + Bicyclo[2.1.0]pent-2-ene = Cyclopentane

By formula: 2H2 + C5H6 = C5H10

Quantity Value Units Method Reference Comment
Δr-410. ± 2.kJ/molChydRoth, Klarner, et al., 1980liquid phase; solvent: Heptane; ALS

Cyclopentane + Iodine = 2Hydrogen iodide + Cyclopentene

By formula: C5H10 + I2 = 2HI + C5H8

Quantity Value Units Method Reference Comment
Δr102.1kJ/molEqkFuruyama, Golden, et al., 1970gas phase; ALS

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-1334
NIST MS number 228237

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Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedSE-30160.572.Kurbatova, Finkelstein, et al., 2004Chromaton N-AW; Column length: 1. m
PackedApiezon L160.587.Kurbatova, Finkelstein, et al., 2004Chromaton N-AW; Column length: 1. m; Large deviations from similar measurements
PackedC78, Branched paraffin130.587.7Dallos, Sisak, et al., 2000He; Column length: 3.3 m
CapillaryOV-1010.558.Skrbic, 1997 
CapillaryBPX-530.572.Aflalaye, Sternberg, et al., 199512. m/0.15 mm/0.25 μm, H2
CapillaryBPX-530.573.Aflalaye, Sternberg, et al., 199512. m/0.15 mm/0.25 μm, H2
CapillaryCP Sil 260.574.3Estel, Mohnke, et al., 1995100. m/0.25 mm/0.25 μm
CapillaryOV-101150.582.4Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
CapillaryOV-101180.591.0Cha and Lee, 1994Column length: 20. m; Column diameter: 0.5 mm
CapillarySqualane25.562.Hilal, Carreira, et al., 1994 
CapillaryDB-160.567.8Krupcik, Skacani, et al., 1994H2; Phase thickness: 0.25 μm
CapillaryPONA60.568.0Krupcik, Skacani, et al., 1994H2; Phase thickness: 0.5 μm
CapillaryPONA60.568.0Krupcik, Skacani, et al., 1994H2; Phase thickness: 0.5 μm
CapillaryDB-160.568.3Krupcik, Skacani, et al., 1994H2; Phase thickness: 1. μm
CapillaryOV-10160.568.4Krupcik, Skacani, et al., 1994H2; Phase thickness: 0.2 μm
CapillaryCP Sil 5 CB20.562.6Do and Raulin, 199225. m/0.15 mm/2. μm, H2
PackedC78, Branched paraffin130.587.6Reddy, Dutoit, et al., 1992Chromosorb G HP; Column length: 3.3 m
PackedApolane130.588.Dutoit, 1991Column length: 3.7 m
CapillaryOV-10140.565.Laub and Purnell, 1988 
CapillaryOV-10160.568.Laub and Purnell, 1988 
CapillaryOV-10180.572.Laub and Purnell, 1988 
CapillarySqualane50.566.2Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillarySqualane70.587.9Lunskii and Paizanskaya, 1988He; Column length: 50. m; Column diameter: 0.22 mm
CapillarySqualane50.566.5Papazova, Milina, et al., 1988Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-10140.565.6Boneva and Dimov, 1986100. m/0.27 mm/0.9 μm
CapillaryOV-10150.566.1Boneva and Dimov, 1986100. m/0.27 mm/0.9 μm
CapillaryOV-10160.569.4Boneva and Dimov, 1986100. m/0.27 mm/0.9 μm
CapillaryOV-10170.569.9Boneva and Dimov, 1986100. m/0.27 mm/0.9 μm
CapillaryOV-1100.574.5Anders, Anders, et al., 198555. m/0.21 mm/0.35 μm, N2
CapillaryOV-10130.563.Chien, Furio, et al., 1983 
CapillaryOV-10140.565.Chien, Furio, et al., 1983 
CapillaryOV-10150.566.Chien, Furio, et al., 1983 
CapillaryOV-10160.568.Chien, Furio, et al., 1983 
CapillaryOV-10170.570.Chien, Furio, et al., 1983 
CapillaryOV-10180.572.Chien, Furio, et al., 1983 
CapillaryDB-160.567.8Lubeck and Sutton, 1983Column length: 60. m; Column diameter: 0.264 mm
CapillaryDB-160.568.3Lubeck and Sutton, 198360. m/0.259 mm/1. μm
PackedSE-30100.577.Winskowski, 1983Gaschrom Q; Column length: 2. m
CapillaryOV-150.566.Anders, Scheller, et al., 1982Column length: 55. m; Column diameter: 0.21 mm
CapillarySE-30130.582.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillarySE-3080.570.Bredael, 1982Column length: 100. m; Column diameter: 0.5 mm
CapillaryOV-10150.567.Johansen and Ettre, 1982100. m/0.27 mm/0.20 μm
CapillaryOV-10150.566.Johansen and Ettre, 198255. m/0.27 mm/0.9 μm
CapillarySF-9650.565.Johansen and Ettre, 198291.4 m/0.31 mm/0.20 μm
PackedSqualane100.568.Nabivach and Kirilenko, 1980He, Chromaton N-AW-HMDS; Column length: 1. m
CapillarySqualane86.568.8Nabivach and Kirilenko, 1979N2; Column length: 50. m
CapillarySqualane50.565.55Pacáková and Koslík, 197850. m/0.2 mm/0.5 μm, N2
CapillarySqualane40.563.3Stopp, Engewald, et al., 1978Column length: 70. m; Column diameter: 0.23 mm
PackedApolane70.575.9Riedo, Fritz, et al., 1976He, Chromosorb; Column length: 2.4 m
CapillarySqualane100.573.Dielmann, Schwengers, et al., 1974Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane120.576.Dielmann, Schwengers, et al., 1974Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane60.567.Dielmann, Schwengers, et al., 1974Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane80.570.Dielmann, Schwengers, et al., 1974Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane50.566.Rijks and Cramers, 1974N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.568.Rijks and Cramers, 1974N2; Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane100.573.Besson and Gäumann, 1973Column length: 50. m; Column diameter: 0.25 mm
CapillaryApiezon L100.588.Besson and Gäumann, 1973Column length: 50. m; Column diameter: 0.25 mm
CapillaryOV-10150.566.Pacáková, Hoch, et al., 197325. m/0.25 mm/1.39 μm, N2
CapillaryOV-10150.567.Pacáková, Hoch, et al., 197325. m/0.25 mm/1.39 μm, N2
CapillaryOV-10160.568.Pacáková, Hoch, et al., 197325. m/0.25 mm/1.39 μm, N2
CapillaryOV-10160.568.Pacáková, Hoch, et al., 197325. m/0.25 mm/1.39 μm, N2
CapillarySqualane86.572.Agrawal, Tesarík, et al., 1972N2, Celite 545; Column length: 50. m; Column diameter: 0.3 mm
CapillaryVacuum Grease Oil (VM-4)35.568.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)45.570.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)50.571.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)58.573.Sidorov, Petrova, et al., 1972 
CapillaryVacuum Grease Oil (VM-4)68.574.Sidorov, Petrova, et al., 1972 
CapillarySqualane70.566.3Dimov and Schopov, 1971Column length: 100. m; Column diameter: 0.25 mm
PackedSE-3075.571.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m
PackedVacuum Grease Oil (VM-4)35.568.Sidorov, Ivanova, et al., 1971 
CapillarySqualane70.568.Cramers, Rijks, et al., 1970Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.568.Cramers, Rijks, et al., 1970Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane70.568.Cramers, Rijks, et al., 1970Column length: 100. m; Column diameter: 0.25 mm
PackedSE-30130.572.Mitra and Saha, 1970N2, Chromosorb W; Column length: 6.1 m
PackedSqualane27.563.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane49.566.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane67.569.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane86.572.Hively and Hinton, 1968He, Chromosorb P; Column length: 15. m; Column diameter: 0.25 mm
PackedSqualane22.562.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane30.563.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane40.564.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane55.568.Evans, 1966Untreated celite; Column length: 1.8 m
PackedSqualane70.570.Evans, 1966Untreated celite; Column length: 1.8 m
CapillarySqualane120.578.Schomburg, 1966 
CapillarySqualane80.568.Schomburg, 1966 
PackedMethyl Silicone130.562.Antheaume and Guiochon, 1965 
PackedSqualane150.599.Schomburg, 1964 
PackedApiezon L130.587.Wehrli and Kováts, 1959Celite; Column length: 2.25 m
PackedApiezon L70.571.Wehrli and Kováts, 1959Celite; Column length: 2.25 m

Kovats' RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101557.Hayes and Pitzer, 1982110. m/0.25 mm/0.20 μm, He, 1. K/min; Tstart: 35. C; Tend: 200. C
CapillaryApiezon L576.Louis, 1971N2, 1. K/min; Column length: 50. m; Column diameter: 0.25 mm; Tstart: 60. C

Kovats' RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryPetrocol DH-100566.5Haagen-Smit Laboratory, 1997He; Column length: 100. m; Column diameter: 0.2 mm; Program: 5C(10min) => 5C/min => 50C(48min) => 1.5C/min => 195C(91min)
CapillaryDB-1563.Hoekman, 199360. m/0.32 mm/1.0 μm, He; Program: -40 C for 12 min; -40 - 125 C at 3 deg.min; 125-185 C at 6 deg/min; 185 - 220 C at 20 deg/min; hold 220 C for 2 min

Kovats' RI, polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedPEG-2000150.694.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000152.700.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000179.710.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000180.698.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000200.700.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m
PackedPEG-2000200.720.Anderson, Jurel, et al., 1973He, Celite 545 (44-60 mesh); Column length: 3. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPetrocol DH553.7Censullo, Jones, et al., 200350. m/0.25 mm/0.5 μm, He, 35. C @ 10. min, 3. K/min, 200. C @ 10. min
CapillarySPB-1580.29LECO Corporation, 200330. m/0.25 mm/0.25 μm, 40. C @ 2. min, 10. K/min, 250. C @ 2. min
CapillaryDB-5563.2Xu, van Stee, et al., 200330. m/0.25 mm/1. μm, He, 2.5 K/min; Tstart: 50. C; Tend: 200. C
CapillaryOV-101556.6Yin, Liu, et al., 2001N2, 1. K/min; Column length: 80. m; Column diameter: 0.22 mm; Tstart: 30. C; Tend: 130. C
CapillaryPetrocol DH554.33Subramaniam, Bochniak, et al., 1994100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH554.33Subramaniam, Bochniak, et al., 1994100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH554.13White, Douglas, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH554.24White, Douglas, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryPetrocol DH554.White, Hackett, et al., 1992100. m/0.25 mm/0.5 μm, He, 1. K/min; Tstart: 30. C; Tend: 220. C
CapillaryOV-101557.Hayes and Pitzer, 1981108. m/0.25 mm/0.2 μm, 1. K/min; Tstart: 35. C; Tend: 200. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryDB-1559.Peng, 200015. m/0.53 mm/1. μm, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min)
PackedSE-30564.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)
PackedSE-30564.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Normal alkane RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryOV-10140.565.Li and Deng, 1998N2; Column length: 51. m; Column diameter: 0.25 mm
CapillarySE-5450.571.Xieyun, Maoqi, et al., 1996N2; Column length: 40. m; Column diameter: 0.25 mm
CapillaryMethyl Silicone50.566.N/AN2; Column length: 74.6 m; Column diameter: 0.28 mm
CapillaryOV-10150.566.Wu and Lu, 1984 
CapillaryOV-10170.569.Wu and Lu, 1984 
PackedSynachrom150.520.Dufka, Malinsky, et al., 1971Helium, Synachrom (60-80 mesh); Column length: 1.5 m
PackedSynachrom150.524.Dufka, Malinsky, et al., 1971Helium, Synachrom (60-80 mesh); Column length: 1.5 m
CapillarySqualane86.560.Vigdergauz and Martynov, 1971He; Column length: 150. m; Column diameter: 0.35 mm

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryPolydimethyl siloxane: CP-Sil 5 CB560.Bramston-Cook, 201360. m/0.25 mm/1.0 μm, Helium, 45. C @ 1.45 min, 3.6 K/min, 210. C @ 2.72 min
CapillaryPetrocol DH564.Supelco, 2012100. m/0.25 mm/0.50 μm, Helium, 20. C @ 15. min, 15. K/min, 220. C @ 30. min
CapillaryBP-1562.Health Safety Executive, 200050. m/0.22 mm/0.75 μm, He, 5. K/min; Tstart: 50. C; Tend: 200. C
CapillaryDB-5MS554.5Shoenmakers, Oomen, et al., 200030. m/0.25 mm/0.25 μm, He, 40. C @ 1. min, 3. K/min; Tend: 250. C
CapillaryOV-101564.Orav, Kailas, et al., 199950. m/0.20 mm/0.50 μm, Helium, 30. C @ 6. min, 1. K/min; Tend: 100. C
CapillarySE-54554.Guan, Li, et al., 199560. C @ 2. min, 4. K/min; Column length: 50. m; Column diameter: 0.32 mm; Tend: 200. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySqualane527.Chen, 2008Program: not specified
CapillarySqualane562.Chen, 2008Program: not specified
CapillaryMethyl Silicone563.Blunden, Aneja, et al., 200560. m/0.32 mm/1.0 μm, Helium; Program: -50 0C (2 min) 8 0C/min -> 200 0C (7.75 min) 25 0C -> 225 0C (8 min)
CapillaryApiezon L587.Finkelstein, Kurbatova, et al., 2002Program: not specified
CapillaryPONA566.Perkin Elmer Instruments, 2002Column length: 100. m; Phase thickness: 0.50 μm; Program: not specified
CapillaryMethyl Silicone587.N/AProgram: not specified
CapillaryDB-1568.Zhu and Wang, 2001Program: not specified
CapillaryMethyl Silicone570.Zenkevich, 2000Program: not specified
CapillaryMethyl Silicone564.Spieksma, 1999Program: not specified
CapillaryMethyl Silicone570.Zenkevich, 1998Program: not specified
CapillaryMethyl Silicone570.Zenkevich, 1996Program: not specified
CapillaryDB-1560.Ciccioli, Cecinato, et al., 199460. m/0.32 mm/0.25 μm; Program: not specified
CapillaryOV-101558.Skrbic and Cvejanov, 1993Program: not specified
CapillarySPB-1533.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C
CapillarySE-52572.van Langenhove and Schamp, 1986Column length: 100. m; Column diameter: 0.50 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.557.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.570.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
CapillaryOV-1, SE-30, Methyl silicone, SP-2100, OV-101, DB-1, etc.577.Waggott and Davies, 1984Hydrogen; Column length: 50. m; Column diameter: 0.32 mm; Program: not specified
PackedSE-30573.Robinson and Odell, 1971N2, Chromosorb W; Column length: 6.1 m; Program: 50C910min) => 20C/min => 90(6min) => 10C/min => 150C(hold)
PackedSqualane564.Robinson and Odell, 1971N2, Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min => 35 => 4C/min => 95C(hold)
PackedSE-30573.Robinson and Odell, 1971, 2Chrom W; Column length: 6.1 m; Program: 50C(10min) => 20C/min(2min) => 90C(6min) => 10C/min(6min) => (hold at 150C)
PackedSqualane564.Robinson and Odell, 1971, 2Embacel; Column length: 3.0 m; Program: 25C(5min) => 2C/min(5min) => 4C/min(15min) => (hold at 95C)

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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McCullough J.P., 1959
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Kurbatova, Finkelstein, et al., 2004
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Aflalaye, Sternberg, et al., 1995
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Dutoit, J., Gas chromatographic retention behaviour of some solutes on structurally similar polar and non-polar stationary phases, J. Chromatogr., 1991, 555, 1-2, 191-204, https://doi.org/10.1016/S0021-9673(01)87179-X . [all data]

Laub and Purnell, 1988
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Papazova, Milina, et al., 1988
Papazova, D.; Milina, R.; Dimov, N., Comparative evaluation of retention of hydrocarbons present in the C5-petroleum fraction of methylsilicone and squalane phases, Chromatographia, 1988, 25, 3, 177-180, https://doi.org/10.1007/BF02316441 . [all data]

Boneva and Dimov, 1986
Boneva, S.; Dimov, N., Unified retention index of hydrocarbons separated on dimethylsilicone OV-101, Chromatographia, 1986, 21, 12, 697-700, https://doi.org/10.1007/BF02313682 . [all data]

Anders, Anders, et al., 1985
Anders, G.; Anders, K.; Engewald, W., Identification of non-branched alkenylcycloalkanes with a terminal double bond from retention index increments, Chromatographia, 1985, 20, 2, 83-86, https://doi.org/10.1007/BF02280602 . [all data]

Chien, Furio, et al., 1983
Chien, C.-F.; Furio, D.L.; Kopecni, M.M.; Laub, R.J., Specific Retention Volumes and Retention Indices of Selected Hydrocarbon Solutes with OV-101 and SP-2100 Polydimethylsiloxane Solvents, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 10, 577-580, https://doi.org/10.1002/jhrc.1240061013 . [all data]

Lubeck and Sutton, 1983
Lubeck, A.J.; Sutton, DL., Kovats retention indices of selected hydrocarbons through C10 on bonded phase fused silica capillaries, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1983, 6, 6, 328-332, https://doi.org/10.1002/jhrc.1240060612 . [all data]

Winskowski, 1983
Winskowski, J., Gaschromatographische Identifizierung von Stoffen anhand von Indexziffem und unterschiedlichen Detektoren, Chromatographia, 1983, 17, 3, 160-165, https://doi.org/10.1007/BF02271041 . [all data]

Anders, Scheller, et al., 1982
Anders, G.; Scheller, M.; Schuhler, C.; Struppe, H.G., Zur Vorausberechnung von Bruttoretentioszeiten bei temperaturprogramierter Gaschromatographie mit Hilfe isotherm bestimmter Retentionsindices und einer Anpassung an experimentelle Retentionszeiten, Chromatographia, 1982, 15, 1, 43-47, https://doi.org/10.1007/BF02269039 . [all data]

Bredael, 1982
Bredael, P., Retention indices of hydrocarbons on SE-30, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1982, 5, 6, 325-328, https://doi.org/10.1002/jhrc.1240050610 . [all data]

Johansen and Ettre, 1982
Johansen, N.G.; Ettre, L.S., Retention index values of hydrocarbons on open-tubular columns coated with methylsilicone liquid phases, Chromatographia, 1982, 15, 10, 625-630, https://doi.org/10.1007/BF02279488 . [all data]

Nabivach and Kirilenko, 1980
Nabivach, V.M.; Kirilenko, A.V., Relationship between the gas chromatographic behaviour and the molecular structure of hydrocarbon samples and various stationary phases. Part II. Correlation between the retention index, physicochemical properties and molecular structure, Chromatographia, 1980, 13, 2, 93-100, https://doi.org/10.1007/BF02263060 . [all data]

Nabivach and Kirilenko, 1979
Nabivach, V.M.; Kirilenko, A.V., The use of retention indices for identifying the components of crude benzene, Solid Fuel Chem. (Engl. Transl.), 1979, 13, 3, 82-87. [all data]

Pacáková and Koslík, 1978
Pacáková, V.; Koslík, V., Capillary reaction gas chromatography. I. Catalytic decomposition of hydrocarbons, Chromatographia, 1978, 11, 5, 266-273, https://doi.org/10.1007/BF02282952 . [all data]

Stopp, Engewald, et al., 1978
Stopp, I.; Engewald, W.; Kühn, H.; Welsch, Th., Molekülstruktur und retentionsverhalten. VIII. Zum gaschromatographischen retentionsverhalten von dicyclopentadienderivaten, J. Chromatogr., 1978, 147, 21-30, https://doi.org/10.1016/S0021-9673(00)85113-4 . [all data]

Riedo, Fritz, et al., 1976
Riedo, F.; Fritz, D.; Tarján, G.; Kováts, E.Sz., A tailor-made C87 hydrocarbon as a possible non-polar standard stationary phase for gas chromatography, J. Chromatogr., 1976, 126, 63-83, https://doi.org/10.1016/S0021-9673(01)84063-2 . [all data]

Dielmann, Schwengers, et al., 1974
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Notes

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