Adamantane
- Formula: C10H16
- Molecular weight: 136.2340
- IUPAC Standard InChIKey: ORILYTVJVMAKLC-UHFFFAOYSA-N
- CAS Registry Number: 281-23-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tricyclo[3.3.1.1(3,7)]decane; Tricyclo(3,3,1,1,3,7)-decane; tricyclo[3.3.1.13,7]decane
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Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.)
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
References
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mokbel, Ruzicka, et al., 2000
Mokbel, Ilham; Ruzicka, Kvetoslav; Majer, Vladimir; Ruzicka, Vlastimil; Ribeiro, Madeleine; Jose, Jacques; Zábranský, Milan,
Vapor pressures and thermal data for three high-boiling compounds of petroleum interest: 1-phenyldodecane, (5α)-cholestane, adamantane,
Fluid Phase Equilibria, 2000, 169, 2, 191-207, https://doi.org/10.1016/S0378-3812(99)00342-8
. [all data]
Chickos, Hesse, et al., 1998
Chickos, James; Hesse, Donald; Hosseini, Sarah; Nichols, Gary; Webb, Paul,
Sublimation enthalpies at 298.15K using correlation gas chromatography and differential scanning calorimetry measurements,
Thermochimica Acta, 1998, 313, 2, 101-110, https://doi.org/10.1016/S0040-6031(97)00432-2
. [all data]
Jochems, Dekker, et al., 1982
Jochems, R.; Dekker, H.; Mosselman, C.; Somsen, G.,
The use of the LKB 8721-3 vaporization calorimeter to measure enthalpies of sublimation. The enthalpies of sublimation of bicyclo[2.2.1]hept-2-ene (norbornene), bicyclo[2.2.1]heptane (norbornane), and tricyclo[3.3.1.13,7]decane (adamantane),
J. Chem. Thermodyn., 1982, 14, 395-398. [all data]
Clark, Knox, et al., 1979
Clark, T.; Knox, T.M.O.; McKervey, M.A.; Mackle, H.; Rooney, J.J.,
Thermochemistry of bridged-ring substances. Enthalpies of formation of some diamondoid hydrocarbons and of perhydroquinacene. Comparisons with data from empirical force field calculations,
J. Am. Chem. Soc., 1979, 101, 2404-2410. [all data]
Clark, Knox, et al., 1975
Clark, T.; Knox, T.M.; Mackle, H.; McKervey, M.A.; Rooney, J.J.,
Calorimetric evaluation of enthalpies of formation of some bridged-ring hydrocarbons. Comparison with data from empirical force field calculations.,
J. Am. Chem. Soc., 1975, 97, 3835-3836. [all data]
Clark, Knox, et al., 1975, 2
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J.,
Heats of sublimation of some cage hydrocarbons by a temperature scanning technique,
J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107
. [all data]
Chickos, Hosseini, et al., 1993
Chickos, James S.; Hosseini, Sarah; Hesse, Donald G.; Liebman, Joel F.,
Heat capacity corrections to a standard state: a comparison of new and some literature methods for organic liquids and solids,
Struct Chem, 1993, 4, 4, 271-278, https://doi.org/10.1007/BF00673701
. [all data]
Boyd, Sanwal, et al., 1971
Boyd, R.H.; Sanwal, S.N.; Shary-Tehrany, S.; McNally, D.,
The thermochemistry, thermodynamic functions, and molecular structures of some cyclic hydrocarbons,
J. Phys. Chem., 1971, 75, 1264-1271. [all data]
Butler, Carson, et al., 1971
Butler, R.S.; Carson, A.S.; Laye, P.G.; Steele, W.V.,
The enthalpy of formation of adamantane,
J. Chem. Thermodyn., 1971, 3, 277-280. [all data]
Mansson, Rapport, et al., 1970
Mansson, M.; Rapport, N.; Westrum, E.F., Jr.,
Enthalpies of formation of globular molecules. I. Adamantane and hexamethylenetetramine,
J. Am. Chem. Soc., 1970, 92, 7296-7299. [all data]
Schleyer, Williams, et al., 1970
Schleyer, Paul von R.; Williams, James Earl.; Blanchard, K.R.,
Evaluation of strain in hydrocarbons. The strain in adamantane and its origin,
J. Am. Chem. Soc., 1970, 92, 8, 2377-2386, https://doi.org/10.1021/ja00711a030
. [all data]
Westrum, Mansson, et al., 1970
Westrum, Edgar F.; Mansson, Margret.; Rapport, Naomi.,
Enthalpies of formation of globular molecules. I. Adamantane and hexamethylenetetramine,
J. Am. Chem. Soc., 1970, 92, 25, 7296-7299, https://doi.org/10.1021/ja00728a011
. [all data]
Bratton, Szilard, et al., 1967
Bratton, W. Kevin; Szilard, I.; Cupas, Chris A.,
Enthalpy of sublimation of adamantane,
J. Org. Chem., 1967, 32, 6, 2019-2021, https://doi.org/10.1021/jo01281a083
. [all data]
Notes
Go To: Top, Enthalpy of sublimation at standard conditions (nominally 298.15 K, 1 atm.), References
- Symbols used in this document:
ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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