Adamantane
- Formula: C10H16
- Molecular weight: 136.2340
- IUPAC Standard InChIKey: ORILYTVJVMAKLC-UHFFFAOYSA-N
- CAS Registry Number: 281-23-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Tricyclo[3.3.1.1(3,7)]decane; Tricyclo(3,3,1,1,3,7)-decane; tricyclo[3.3.1.13,7]decane
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Kovats' RI, non-polar column, isothermal
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Column type | Packed | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | PMS-1000 | SE-30 | SE-30 | SE-30 | C78, Branched paraffin |
Column length (m) | 2. | 1. | 1. | 1. | 3.3 |
Carrier gas | N2 | N2 | He | ||
Substrate | Chromaton N-AW-DMCS | Chromaton N-AW | N-AW Chromaton | CHromaton N-AW | |
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 120. | 160. | 150. | 150. | 130. |
I | 1121. | 1117. | 1120. | 1120. | 1136.9 |
Reference | Arutyunov, Kudryashov, et al., 2004 | Kurbatova, Finkelstein, et al., 2004 | L'vova, Kurbatova, et al., 2001 | Yashkin, Kurbatova, et al., 2001 | Dallos, Sisak, et al., 2000 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed | Packed |
---|---|---|---|---|---|
Active phase | PMS-1000 | Apiezon L | Apiezon L | Apiezon L | PMS-1000 |
Column length (m) | 1. | 1. | 1. | 1. | 1. |
Carrier gas | N2 | N2 | N2 | ||
Substrate | Chromatron N-AW | Chromatron N-AW | Chromaton N-AW | Chromaton N-AW | Chromaton N-AW |
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 160. | 160. | 200. | 200. | 160. |
I | 1149. | 1116. | 1116. | 1116. | 1149. |
Reference | Kurbatova, Moiseev, et al., 1999 | Kurbatova, Moiseev, et al., 1999 | Kurbatova, Yashkin, et al., 1999 | Kurbatova, Moiseev, et al., 1998 | Kurbatova, Moiseev, et al., 1998, 2 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | C78, Branched paraffin | Squalane | SE-30 | SE-30 | SE-30 |
Column length (m) | 3.3 | 100. | |||
Carrier gas | He | ||||
Substrate | Chromosorb G HP | ||||
Column diameter (mm) | 0.25 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 130. | 110. | 110. | 120. | 130. |
I | 1135.3 | 1095.2 | 1113. | 1117. | 1120. |
Reference | Reddy, Dutoit, et al., 1992 | Bender, Said, et al., 1986 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | Squalane | Squalane | Squalane |
Column length (m) | |||||
Carrier gas | |||||
Substrate | |||||
Column diameter (mm) | |||||
Phase thickness (μm) | |||||
Temperature (C) | 145. | 150. | 110. | 125. | 140. |
I | 1118. | 1116. | 1095. | 1104. | 1114. |
Reference | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 | Bogoslovsky, Anvaer, et al., 1978 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Packed | Packed | Packed | Packed | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 6.1 | 6.1 | 6.1 | 6.1 | |
Carrier gas | N2 | N2 | N2 | H2 | |
Substrate | Chrom W | Chrom W | Chrom W | ||
Column diameter (mm) | 3.18 | ||||
Phase thickness (μm) | |||||
Temperature (C) | 150. | 120. | 130. | 140. | 130. |
I | 1116. | 1117. | 1120. | 1125. | 1120. |
Reference | Shlyakhov, Anvaer, et al., 1975 | Mitra, Mohan, et al., 1974 | Mitra, Mohan, et al., 1974 | Mitra, Mohan, et al., 1974 | Mitra, Mohan, et al., 1974, 2 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | SE-30 | SE-30 | SE-30 | Squalane | Squalane |
Column length (m) | 6.1 | 6.1 | 6.1 | 50. | 50. |
Carrier gas | H2 | H2 | H2 | N2 | N2 |
Substrate | |||||
Column diameter (mm) | 3.18 | 3.18 | 3.18 | 0.2 | 0.2 |
Phase thickness (μm) | |||||
Temperature (C) | 140. | 150. | 160. | 110. | 125. |
I | 1128. | 1131. | 1130. | 1095. | 1104. |
Reference | Mitra, Mohan, et al., 1974, 2 | Mitra, Mohan, et al., 1974, 2 | Mitra, Mohan, et al., 1974, 2 | Hála, Eyem, et al., 1970 | Hála, Eyem, et al., 1970 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
Column type | Capillary | Capillary | Capillary | Capillary | Capillary |
---|---|---|---|---|---|
Active phase | Squalane | SE-30 | SE-30 | SE-30 | SE-30 |
Column length (m) | 50. | 50. | 50. | 50. | 50. |
Carrier gas | N2 | N2 | N2 | N2 | N2 |
Substrate | |||||
Column diameter (mm) | 0.2 | 0.27 | 0.27 | 0.27 | 0.27 |
Phase thickness (μm) | |||||
Temperature (C) | 140. | 145. | 160. | 175. | 190. |
I | 1114. | 1118. | 1132. | 1143. | 1153. |
Reference | Hála, Eyem, et al., 1970 | Burkhard, Vais, et al., 1969 | Burkhard, Vais, et al., 1969 | Burkhard, Vais, et al., 1969 | Burkhard, Vais, et al., 1969 |
Comment | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI | MSDC-RI |
References
Go To: Top, Kovats' RI, non-polar column, isothermal, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Arutyunov, Kudryashov, et al., 2004
Arutyunov, Y.I.; Kudryashov, S.Y.; Onuchak, L.A.,
Analysis of Mixtures Containing Unknown Components by Gas Chromatography: Determination of Molecular Mass,
J. Anal. Chem. USSR (Engl. Transl.), 2004, 59, 4, 358-365. [all data]
Kurbatova, Finkelstein, et al., 2004
Kurbatova, S.V.; Finkelstein, E.E.; Kolosova, E.A.; Kartashev, A.V.; Rashkin, S.V.,
Structural analogy method in studies of adamantanes,
J. Struct. Chem., 2004, 45, 1, 144-150, https://doi.org/10.1023/B:JORY.0000041513.82837.4e
. [all data]
L'vova, Kurbatova, et al., 2001
L'vova, N.Yu.; Kurbatova, S.V.; Yashkin, S.N.; Kolosova, E.A.,
Gas chromatography of halogenated adamantanes,
Russ. J. Phys. Chem. (Engl. Transl.), 2001, 75, 12, 2053-2056. [all data]
Yashkin, Kurbatova, et al., 2001
Yashkin, S.N.; Kurbatova, S.V.; Buryak, A.K.,
Gas chromatography of halogenated adamantanes,
Russ. Chem. Bull. (Engl. Transl.), 2001, 50, 5, 828-832, https://doi.org/10.1023/A:1011350908009
. [all data]
Dallos, Sisak, et al., 2000
Dallos, A.; Sisak, A.; Kulcsár, Z.; Kováts, E.,
Pair-wise interactions by gas chromatography VII. Interaction free enthalpies of solutes with secondary alcohol groups,
J. Chromatogr. A, 2000, 904, 2, 211-242, https://doi.org/10.1016/S0021-9673(00)00908-0
. [all data]
Kurbatova, Moiseev, et al., 1999
Kurbatova, S.V.; Moiseev, I.K.; Kudryashov, S.Yu.; Yashkin, S.N.; Postnikova, I.V.,
Chromatographic examination of the intermediate products of midantane synthesis,
J. Anal. Chem. USSR (Engl. Transl.), 1999, 54, 1, 75-77. [all data]
Kurbatova, Yashkin, et al., 1999
Kurbatova, S.V.; Yashkin, S.N.; Moiseev, I.K.; Zemtsova, M.N.,
A study of the cell effect for adamantane derivatives by gas-liquid chromatography,
Russ. J. Phys. Chem. (Engl. Transl.), 1999, 73, 9, 1486-1489. [all data]
Kurbatova, Moiseev, et al., 1998
Kurbatova, S.V.; Moiseev, I.K.; Zemtsova, M.N.; Kudryashov, S.Yu.,
Gas chromatography of aminoadamantanes,
J. Anal. Chem. USSR (Engl. Transl.), 1998, 53, 8, 732-734. [all data]
Kurbatova, Moiseev, et al., 1998, 2
Kurbatova, S.V.; Moiseev, I.K.; Klimochkin, Yu.N.; Arutyunov, Yu.N.,
Chromatography analysis of intermediates in the synthesis of remantadin,
J. Anal. Chem. USSR (Engl. Transl.), 1998, 53, 9, 865-868. [all data]
Reddy, Dutoit, et al., 1992
Reddy, K.S.; Dutoit, J.-Cl.; Kovats, E. sz.,
Pair-wise interactions by gas chromatography. I. Interaction free enthalpies of solutes with non-associated primary alcohol groups,
J. Chromatogr., 1992, 609, 1-2, 229-259, https://doi.org/10.1016/0021-9673(92)80167-S
. [all data]
Bender, Said, et al., 1986
Bender, A.O.; Said, E.Z.; Abdulsada, A.K.,
Gas chromatographic identification of adamantanes in some Iraqi crude oils,
Analyst, 1986, 111, 5, 575-576, https://doi.org/10.1039/an9861100575
. [all data]
Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S.,
Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]
Shlyakhov, Anvaer, et al., 1975
Shlyakhov, A.F.; Anvaer, B.I.; Zolotareva, O.V.; Romina, N.N.; Novikova, N.V.; Koreshkova, R.I.,
On the possibility of group indentification of hydrocarbons by gas chromatography from temperature coefficients of retention indices,
Zh. Anal. Khim., 1975, 30, 788-792. [all data]
Mitra, Mohan, et al., 1974
Mitra, G.D.; Mohan, G.; Sinha, A.,
Advances in the utilization of the retention index system for characterizing hydrocarbons in complex mixtures by gas chromatography,
J. Chromatogr., 1974, 99, 215-230, https://doi.org/10.1016/S0021-9673(00)90857-4
. [all data]
Mitra, Mohan, et al., 1974, 2
Mitra, G.D.; Mohan, G.; Sinha, A.,
Gas chromatographic analysis of complex hydrocarbon mixtures,
J. Chromatogr. A, 1974, 91, 633-648, https://doi.org/10.1016/S0021-9673(01)97944-0
. [all data]
Hála, Eyem, et al., 1970
Hála, S.; Eyem, J.; Burkhard, J.; Landa, S.,
Retention indices of adamantanes,
J. Chromatogr. Sci., 1970, 8, 4, 203-209, https://doi.org/10.1093/chromsci/8.4.203
. [all data]
Burkhard, Vais, et al., 1969
Burkhard, J.; Vais, J.; Vodicka, L.; Landa, S.,
Adamantane and its derivatives. XVI. The gas chromatographic characterization of adamantane derivatives,
J. Chromatogr., 1969, 42, 207-218, https://doi.org/10.1016/S0021-9673(01)80617-8
. [all data]
Notes
Go To: Top, Kovats' RI, non-polar column, isothermal, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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