trans-anti-trans-Tetra-decahydroanthracene

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid-70.12 ± 0.68kcal/molCcbFrisch, 1962see Margrave, Frisch, et al., 1963
Quantity Value Units Method Reference Comment
Δcsolid-2066.38 ± 0.54kcal/molCcbFrisch, 1962see Margrave, Frisch, et al., 1963; Corresponding Δfsolid = -70.12 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub17.38 ± 0.79kcal/molVFrisch, 1962see Margrave, Frisch, et al., 1963; ALS

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
15.8284.N/AStephenson and Malanowski, 1987Based on data from 269. to 313. K.; AC
17.4 ± 0.79294.MEMargrave, Frisch, et al., 1963Based on data from 275. to 313. K. See also Cox and Pilcher, 1970.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

trans-anti-trans-Tetra-decahydroanthracene = Anthracene, tetradecahydro-, (4aα,8aα,9aβ,10aα)-

By formula: C14H24 = C14H24

Quantity Value Units Method Reference Comment
Δr-4.15 ± 0.81kcal/molEqkAllinger and Wuesthoff, 1971gas phase

Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 215310

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Frisch, 1962
Frisch, M.A., A high precision calorimeter for ther measurement of small energy differences, Ph.D. Thesis for University of Wisconsin, 1962, 1-100. [all data]

Margrave, Frisch, et al., 1963
Margrave, J.L.; Frisch, M.A.; Bautista, R.G.; Clarke, R.L.; Johnson, W.S., Further studies on the energy difference between the chair and twist forms of cyclohexane, J. Am. Chem. Soc., 1963, 85, 546-548. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]

Allinger and Wuesthoff, 1971
Allinger, N.L.; Wuesthoff, M.T., Conformational analysis. LXXIII. The perhydroanthracenes. An equilibration study, J. Org. Chem., 1971, 36, 2051-2053. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References