trans-anti-trans-Tetra-decahydroanthracene
- Formula: C14H24
- Molecular weight: 192.3404
- IUPAC Standard InChI: InChI=1S/C14H24/c1-2-6-12-10-14-8-4-3-7-13(14)9-11(12)5-1/h11-14H,1-10H2/t11-,12-,13-,14-/m1/s1
- IUPAC Standard InChIKey: GVJFFQYXVOJXFI-AAVRWANBSA-N
- CAS Registry Number: 28071-99-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- Anthracene, tetradecahydro-, (4aα,8aα,9aβ,10aα)-
- Anthracene, tetradecahydro-, (4aα,8aα,9aα,10aα)-
- Perhydroanthracene, (4aα, 8aα, 9aα, 10aβ)-
- Perhydroanthracene, (4aα, 8aβ, 9aα, 10aβ)-
- Anthracene, tetradecahydro-
- Tricyclo[8.4.0.0(3,8)]dodecane, isomer # 1
- Tricyclo[8.4.0.0(3,8)]dodecane, isomer # 2
- Tricyclo[8.4.0.0(3,8)]dodecane, isomer # 3
- Tricyclo[8.4.0.0(3,8)]dodecane, isomer # 4
- Tricyclo[8.4.0.0(3,8)]dodecane, isomer # 5
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Condensed phase thermochemistry data
Go To: Top, Phase change data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -293.4 ± 2.8 | kJ/mol | Ccb | Frisch, 1962 | see Margrave, Frisch, et al., 1963 |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -8645.7 ± 2.3 | kJ/mol | Ccb | Frisch, 1962 | see Margrave, Frisch, et al., 1963; Corresponding ΔfHºsolid = -293.4 kJ/mol (simple calculation by NIST; no Washburn corrections) |
Phase change data
Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 72.7 ± 3.3 | kJ/mol | V | Frisch, 1962 | see Margrave, Frisch, et al., 1963; ALS |
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 66.1 | 284. | N/A | Stephenson and Malanowski, 1987 | Based on data from 269. to 313. K.; AC |
| 72.7 ± 3.3 | 294. | ME | Margrave, Frisch, et al., 1963 | Based on data from 275. to 313. K. See also Cox and Pilcher, 1970.; AC |
Reaction thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
=
By formula: C14H24 = C14H24
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | -17.4 ± 3.4 | kJ/mol | Eqk | Allinger and Wuesthoff, 1971 | gas phase |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Frisch, 1962
Frisch, M.A.,
A high precision calorimeter for ther measurement of small energy differences, Ph.D. Thesis for University of Wisconsin, 1962, 1-100. [all data]
Margrave, Frisch, et al., 1963
Margrave, J.L.; Frisch, M.A.; Bautista, R.G.; Clarke, R.L.; Johnson, W.S.,
Further studies on the energy difference between the chair and twist forms of cyclohexane,
J. Am. Chem. Soc., 1963, 85, 546-548. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press Inc., London, 1970, 643. [all data]
Allinger and Wuesthoff, 1971
Allinger, N.L.; Wuesthoff, M.T.,
Conformational analysis. LXXIII. The perhydroanthracenes. An equilibration study,
J. Org. Chem., 1971, 36, 2051-2053. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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