Norbornane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas-54.9 ± 1.1kJ/molCcbAn, Zhu, et al., 1987ALS
Δfgas-54.7 ± 4.7kJ/molCcbSteele, 1978Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -61.6 ± 3.4 kJ/mol; ALS
Δfgas-52.0kJ/molN/ABoyd, Sanwal, et al., 1971Value computed using ΔfHsolid° value of -92.1±2.2 kj/mol from Boyd, Sanwal, et al., 1971 and ΔsubH° value of 40.1 kj/mol from An, Zhu, et al., 1987.; DRB
Δfgas-52.0kJ/molN/ABedford, Beezer, et al., 1963Value computed using ΔfHsolid° value of -92.1±2.7 kj/mol from Bedford, Beezer, et al., 1963 and ΔsubH° value of 40.1 kj/mol from An, Zhu, et al., 1987.; DRB

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
120.08298.15Walsh R., 1975Selected value of S(298.15 K) is in good agreement with that calculated by force field method [ Boyd R.H., 1971, Lenz T.G., 1989]. Discrepancy with S(500 K) [ Boyd R.H., 1971] amounts to 8.9 J/mol*K. Discrepancies between Cp(T) values calculated by [ Boyd R.H., 1971] and given here amount to 10.7-12.7 J/mol*K in the temperature range 298.15-500 K.; GT
121.00300.
169.62400.
211.21500.
245.14600.
272.92700.
296.06800.
315.56900.
332.171000.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfsolid-95.0 ± 1.1kJ/molCcbAn, Zhu, et al., 1987ALS
Δfsolid-102.0 ± 3.3kJ/molCcbSteele, 1978ALS
Δfsolid-92.1 ± 2.2kJ/molCcbBoyd, Sanwal, et al., 1971ALS
Δfsolid-92.1 ± 2.7kJ/molCcbBedford, Beezer, et al., 1963see also Boyd, Sanwal, et al., 1971; ALS
Quantity Value Units Method Reference Comment
Δcsolid-4374.59 ± 0.97kJ/molCcbAn, Zhu, et al., 1987Corresponding Δfsolid = -94.96 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-4367.5 ± 3.3kJ/molCcbSteele, 1978Corresponding Δfsolid = -102.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcsolid-4377.5 ± 2.2kJ/molCcbBedford, Beezer, et al., 1963see also Boyd, Sanwal, et al., 1971; Corresponding Δfsolid = -92.09 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
151.0298.15Steele, 1978DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil381.KN/ADesty and Whyman, 1957Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus360.KN/ABurwell, Shim, et al., 1957Uncertainty assigned by TRC = 2. K; TRC
Tfus360.9KN/ABirch and Dean, 1954Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Δsub41. ± 5.kJ/molAVGN/AAverage of 8 values; Individual data points

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
40.3 ± 0.4293.GSVerevkin and Emel'yanenko, 2004Based on data from 278. to 308. K.; AC
40.0 ± 0.8305.TSGCClark, Knox, et al., 1975Based on data from 284. to 326. K.; AC
40.1 ± 0.84284.VBoyd, Sanwal, et al., 1971ALS

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
4.45360.8DSCVerevkin and Emel'yanenko, 2004AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + 2-Norbornene = Norbornane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-137. ± 0.4kJ/molChydDoering, Roth, et al., 1988gas phase
Δr-141.5 ± 1.2kJ/molChydRogers, Choi, et al., 1980liquid phase; solvent: Hexane; Author was aware that data differs from previously reported values
Δr-138.6 ± 0.88kJ/molChydTurner, Meador, et al., 1957liquid phase; solvent: Acetic acid

2,5-Norbornadiene + 2Hydrogen = Norbornane

By formula: C7H8 + 2H2 = C7H12

Quantity Value Units Method Reference Comment
Δr-296. ± 1.kJ/molChydDoering, Roth, et al., 1988gas phase
Δr-291.9 ± 1.5kJ/molChydRogers, Choi, et al., 1980liquid phase; solvent: Hexane
Δr-285.0 ± 1.7kJ/molChydTurner, Meador, et al., 1957liquid phase; solvent: Acetic acid

Hydrogen + Tricyclo[2.2.1.0(2,6)]heptane = Norbornane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-130. ± 0.8kJ/molChydFlury, Grob, et al., 1988liquid phase; solvent: Isooctane
Δr-136.3 ± 2.2kJ/molChydRogers, Choi, et al., 1980liquid phase; solvent: Hexane; Author was aware that data differs from previously reported values

2Hydrogen + Tetracyclo[3.2.0.0(2,7).0(4,6)]heptane = Norbornane

By formula: 2H2 + C7H8 = C7H12

Quantity Value Units Method Reference Comment
Δr-384.7 ± 1.8kJ/molChydRogers, Choi, et al., 1980liquid phase; solvent: Hexane
Δr-385.1 ± 2.1kJ/molChydTurner, Goebel, et al., 1968liquid phase; solvent: Acetic acid

Hydrogen + Tricyclo-[3.2.0.0(2,7)]heptane = Norbornane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-220. ± 0.8kJ/molChydFlury, Grob, et al., 1988liquid phase; solvent: Isooctane

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-9198
NIST MS number 235491

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

An, Zhu, et al., 1987
An, X-W.; Zhu, H-P.; Hu, R-H., Heats of combustion and formation of norbornane, Thermochim. Acta, 1987, 121, 473-477. [all data]

Steele, 1978
Steele, W.V., The standard enthalpies of formation of a series of C7, bridged-ring hydrocarbons: norbornane, norbornene, nortricyclene, norbornadiene, and quadricyclane, J. Chem. Thermodyn., 1978, 10, 919-927. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Boyd, Sanwal, et al., 1971
Boyd, R.H.; Sanwal, S.N.; Shary-Tehrany, S.; McNally, D., The thermochemistry, thermodynamic functions, and molecular structures of some cyclic hydrocarbons, J. Phys. Chem., 1971, 75, 1264-1271. [all data]

Bedford, Beezer, et al., 1963
Bedford, A.F.; Beezer, A.E.; Mortimer, C.T.; Springall, H.D., Heats of combustion and molecular structure. Part IX. Bicylo[2,2,1]heptane, 7-oxabicyclo[2,2,1]heptane, and exo- and endo-2-methyl-7-oxabicyclo[2,2,1]heptane, J. Chem. Soc., 1963, 3823-3828. [all data]

Walsh R., 1975
Walsh R., The enthalpy of formation of bicyclo[2.2.1]hepta-2,5-diene. Thermodynamic functions of bicyclo[2.2.1]heptane and bicyclo[2.2.1]hepta-2,5-diene, J. Chem. Thermodyn., 1975, 7, 149-154. [all data]

Boyd R.H., 1971
Boyd R.H., The thermochemistry, thermodynamic functions, and molecular structures of some cyclic hydrocarbons, J. Phys. Chem., 1971, 75, 1264-1271. [all data]

Lenz T.G., 1989
Lenz T.G., Force-field calculations giving accurate conformation, Hf(T), S(T), and Cp(T) for unsaturated acyclic and cyclic hydrocarbons, J. Phys. Chem., 1989, 93, 1588-1592. [all data]

Desty and Whyman, 1957
Desty, D.H.; Whyman, B.H.F., Anal. Chem., 1957, 29, 320. [all data]

Burwell, Shim, et al., 1957
Burwell, R.L.; Shim, B.K.C.; Rowlinson, H.C., The Exchange between Hydrocarbons and Deuterium on Plladium Catalysts, J. Am. Chem. Soc., 1957, 79, 5142. [all data]

Birch and Dean, 1954
Birch, S.F.; Dean, R.A., A Ring Clousre Reaction by Desulfurization with Raney Nickel, Justus Liebigs Ann. Chem., 1954, 585, 234. [all data]

Verevkin and Emel'yanenko, 2004
Verevkin, Sergey P.; Emel'yanenko, Vladimir N., Enthalpy of Formation and Strain of Norbornane from Thermochemical Measurements and from ab Initio Calculations, J. Phys. Chem. A, 2004, 108, 31, 6575-6580, https://doi.org/10.1021/jp0490554 . [all data]

Clark, Knox, et al., 1975
Clark, Timothy; Knox, Trevor; Mackle, Henry; McKervey, M. Anthony; Rooney, John J., Heats of sublimation of some cage hydrocarbons by a temperature scanning technique, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 0, 2107, https://doi.org/10.1039/f19757102107 . [all data]

Doering, Roth, et al., 1988
Doering, W.E.; Roth, W.R.; Breuckmann, R.; Figge, L.; Lennartz, H.-W.; Fessner, W.-D.; Prinzbach, F.H., Verbotene Reaktionen. - [2 + 2]-Cycloreversion starrer Cyclobutane, Chem. Ber., 1988, 121, 1-9. [all data]

Rogers, Choi, et al., 1980
Rogers, D.W.; Choi, L.S.; Girellini, R.S., Heats of hydrogenation and formation of quadricyclene, norbornadiene, norbornene, and nortricyclene, J. Phys. Chem., 1980, 84, 1810-1814. [all data]

Turner, Meador, et al., 1957
Turner, R.B.; Meador, W.R.; Winkler, R.E., Heats of hydrogenation. I. Apparatus and the heats of hydrogenation of bicyclo[2,2,1]heptene, bicyclo[2,2,1]heptadiene, bicyclo[2,2,2]octene and bicyclo[2,2,2]octadiene, J. Am. Chem. Soc., 1957, 79, 4116-4121. [all data]

Flury, Grob, et al., 1988
Flury, P.; Grob, C.A.; Wang, G.Y.; Lennatz, H.-W.; Roth, W.R., 113. Norbornanes. Bridging strain in norbornyl and oxanorbornyl cations, Helv. Chim. Acta, 1988, 71, 1017-1024. [all data]

Turner, Goebel, et al., 1968
Turner, R.B.; Goebel, P.; Mallon, B.J.; Doering, W.E.; Coburn, J.F., Jr.; Pomerantz, M., Heats of hydrogenation. VIII. Compounds with three- and four-membered rings, J. Am. Chem. Soc., 1968, 90, 4315-4322. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References