Phenol, 4-ethyl-2-methoxy-


Normal alkane RI, non-polar column, custom temperature program

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase CP-Sil 5 CBCP-Sil 5 CBPolydimethyl siloxane with 5 % Ph groupsPolydimethyl siloxane with 5 % Ph groupsHP-5 MS
Column length (m) 50.50.  30.
Carrier gas NitrogenNitrogen  Helium
Substrate      
Column diameter (mm) 0.320.32  0.32
Phase thickness (μm) 1.201.20  0.25
Program 36 0C 20 0C/min -> 85 0C 1 0C/min -> 145 0C 3 0C/min -> 250 0C (30 min)36 0C 20 0C/min -> 85 0C 1 0C/min -> 145 0C 3 0C/min -> 250 0Cnot specifiednot specified40 0C (1 min) 3 0C/min -> 150 0C (15 min) 5 0C/min -> 250 0C (5 min)
I 1260.1257.1282.1284.1264.
ReferenceCollin, Nizet, et al., 2012Collin, Nizet, et al., 2012, 2Robinson, Adams, et al., 2012Robinson, Adams, et al., 2012Rodrigues, Hanson, et al., 2012
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase VF-5 MSDB-5ZB-5CP-Sil 5 CbSLB-5MS
Column length (m) 30.30.30.50.10.
Carrier gas HeliumHydrogenHeliumNitrogenHelium
Substrate      
Column diameter (mm) 0.250.320.250.320.18
Phase thickness (μm) 0.250.500.251.200.18
Program not specified40 0C (5 min) 4 0C/min -> 100 0C 6 0C/min -> 220 0C (20 min)45 0C 3 0C/min -> 230 0C (10 min) 10 0C/min -> 270 0C (21 min)40 0C 20 0C/min -> 85 0C 1 0C/min -> 145 0C 3 0C/min -> 250 0C (30 min)not specified
I 1286.1285.1274.1263.1275.
ReferenceSouza, Re-Poppi, et al., 2012San-Juan, Petka, et al., 2010de Simon, Estruelas, et al., 2009Collin, Nizet, et al., 2008Risticevic, Carasek, et al., 2008
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5Polydimethyl siloxaneDB-1HP-5MS
Column length (m) 30.30. 30.30.
Carrier gas    HeliumHe
Substrate      
Column diameter (mm) 0.250.25 0.250.25
Phase thickness (μm) 0.250.25  0.25
Program 40 0C (2 min) 5 0C/min -> 80 0C 7 oC/min -> 160 0C 9 0C/min -> 200 0C 20 0C/min -> 280 0C (10 min)not specifiednot specified120 0C (2 min( 5 0C/min -> 200 0C 10 0C/min -> 290 0C (5 min)40C(1min) => 8C/min => 160C => 12C/min => 300C(5min)
I 1281.1280.1247.1252.1243.
ReferenceZhao, Li, et al., 2008Zhao, Li, et al., 2008RAyne and Eggers, 2007Sung, Stone, et al., 2007Li, Deng, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5SE-30HP-5MSHP-5OV-101
Column length (m) 30. 30.30. 
Carrier gas He HeHe 
Substrate      
Column diameter (mm) 0.25 0.250.25 
Phase thickness (μm) 0.25 0.250.25 
Program 40C(1min) => 9C/min => 130C => 2C/min => 230Cnot specified40C (10min) => 3C/min => 120C => 10C/min => 250C (5min)40C (10min) => 3C/min => 120C => 10C/min => 250C (5min)not specified
I 1270.1265.1280.1277.1246.
ReferenceHamm, Bleton, et al., 2004Vinogradov, 2004Ansorena, Gimeno, et al., 2001Ansorena, Astiasarán, et al., 2000Licker, Acree, et al., 1998
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase DB-5SE-54SE-54
Column length (m) 30.30. 
Carrier gas He  
Substrate    
Column diameter (mm) 0.320.32 
Phase thickness (μm) 0.250.25 
Program 35C(1min) => 40C/min => 60C (1min) => 6C/min => 230C35 0C (2 min) 40 0C/min -> 50 0C (1 min) 6 0C/min -> 230 0Cnot specified
I 1290.1278.1287.
ReferenceMatsui, Guth, et al., 1998Reiners and Grosch, 1998Blank, Sen, et al., 1992
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Normal alkane RI, non-polar column, custom temperature program, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Collin, Nizet, et al., 2012
Collin, S.; Nizet, S.; Gros, J., Le houblonnage a cru des bieres speciales belges est bien plus qu'une simple dissolution des composes aromatiques du houblon (in Flamish), Cerevisia, 2012, 36, 4, 119-124, https://doi.org/10.1016/j.cervis.2011.12.001 . [all data]

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RAyne and Eggers, 2007
RAyne, S.; Eggers, N.J., A new conceptual approach to assisting biomass combustion-derived methoxyphenol structures by using a gas chromatographic retention index method, Anal. Bioanal. Chem., 2007, 389, 2, 555-561, https://doi.org/10.1007/s00216-007-1442-5 . [all data]

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Hamm, Bleton, et al., 2004
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Matsui, Guth, et al., 1998
Matsui, T.; Guth, H.; Grosch, W., A comparative study of potent odorants in peanut, hazelnut, and pumpkin seed oils on the basis of aroma extract dilution analysis (AEDA) and gas chromatography-olfactometry of headspace samples (GCOH), Lipid - Fett, 1998, 100, 2, 51-56, https://doi.org/10.1002/(SICI)1521-4133(199802)100:2<51::AID-LIPI51>3.0.CO;2-W . [all data]

Reiners and Grosch, 1998
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Notes

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