Bicyclo[3.2.0]heptane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil382.4KN/ABlomquist and Kwiatek, 1951Uncertainty assigned by TRC = 1.5 K

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

2Hydrogen + Anti-tricyclo[3.2.0.0(2,4)]hept-6-ene = Bicyclo[3.2.0]heptane

By formula: 2H2 + C7H8 = C7H12

Quantity Value Units Method Reference Comment
Δr-91.1 ± 0.1kcal/molChydRoth, Klaerner, et al., 1983liquid phase; solvent: Isooctane

Hydrogen + Anti-tricyclo[3.2.0.0(2,4)]heptane = Bicyclo[3.2.0]heptane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-55.6 ± 0.3kcal/molChydRoth, Klaerner, et al., 1983liquid phase; solvent: Isooctane

Hydrogen + Syn-tricyclo[3.2.0.0(2,4)]heptane = Bicyclo[3.2.0]heptane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-64.1 ± 0.3kcal/molChydRoth, Klaerner, et al., 1983liquid phase; solvent: Isooctane

2Hydrogen + Bicyclo[3.2.0]hepta-2,6-diene = Bicyclo[3.2.0]heptane

By formula: 2H2 + C7H8 = C7H12

Quantity Value Units Method Reference Comment
Δr-62.6 ± 0.1kcal/molChydRoth, Adamczak, et al., 1991liquid phase

Hydrogen + Bicyclo[3.2.0]hept-1-ene = Bicyclo[3.2.0]heptane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-39.4 ± 0.3kcal/molChydRoth, Adamczak, et al., 1991liquid phase

Hydrogen + cis-Bicyclo[3.2.0]hept-2-ene = Bicyclo[3.2.0]heptane

By formula: H2 + C7H10 = C7H12

Quantity Value Units Method Reference Comment
Δr-27.8 ± 0.1kcal/molChydRoth, Adamczak, et al., 1991liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Blomquist and Kwiatek, 1951
Blomquist, A.T.; Kwiatek, J., The Addition of Ketene to Cyclic Conjugated Dienes, J. Am. Chem. Soc., 1951, 73, 2098-2100. [all data]

Roth, Klaerner, et al., 1983
Roth, W.R.; Klaerner, F.G.; Gerit, F.; Grimme, W.; Koeser, H.G.; Busch, R.; Muskulus, B.; Breuckmann, R.; Scholz, B.P.; Lennartz, H.W., Stereochemistry of the bicyclo[2.1.0]pentane ring opening: thermolysis of tricyclo[3.2.0.0(,)]heptane derivatives, Chem. Ber., 1983, 116, 2717-2737. [all data]

Roth, Adamczak, et al., 1991
Roth, W.R.; Adamczak, O.; Breuckmann, R.; Lennartz, H.-W.; Boese, R., Die Berechnung von Resonanzenergien; das MM2ERW-Kraftfeld, Chem. Ber., 1991, 124, 2499-2521. [all data]


Notes

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