β-D-Glucopyranose, 5TMS derivative
- Formula: C21H52O6Si5
- Molecular weight: 541.0615
- IUPAC Standard InChI: InChI=1S/C21H52O6Si5/c1-28(2,3)22-16-17-18(24-29(4,5)6)19(25-30(7,8)9)20(26-31(10,11)12)21(23-17)27-32(13,14)15/h17-21H,16H2,1-15H3/t17-,18-,19+,20-,21+/m0/s1
- IUPAC Standard InChIKey: PPFHNIVPOLWPCF-JRSUCEMESA-N
- CAS Registry Number: 2775-90-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Stereoisomers:
- α-D-Mannopyranose, 5TMS derivative
- α-D-Glactopyranose, 5TMS derivative
- β-Galactopyranose, TMS
- α-D-Glucopyranose, 5TMS derivative
- α-D-Galactose, TMS
- β-Gulopyranose, TMS
- [2H]Mannose, TMS
- Galactose, TMS
- A-Psicopyranose, TMS
- A-Sorbopyranose, TMS
- B-Psicopyranose, TMS
- B-Sorbopyranose, TMS
- α-Mannose, TMS
- α-Mannopyranose, TMS
- D(+)-Talose, aldol, TMS
- D-Altrose, aldol, TMS
- α-Allopyranose, TMS
- α-Altropyranose, TMS
- α-Gulopyranose, TMS
- α-Idopyranose, TMS
- α-Talopyranose, TMS
- β-Allopyranose, TMS
- β-Altropyranose, TMS
- β-Idopyranose, TMS
- β-Mannopyranose, TMS
- β-Talopyranose, TMS
- D-Glucopyranose, penta-TMS
- α-Glucopyranoside, TMS
- Glucose, TMS # 2
- β-D-(+)-Mannopyranose, 5TMS derivative
- D-(+)-Galactopyranose, 5TMS derivative (isomer 1)
- D-(+)-Galactopyranose, 5TMS derivative (isomer 2)
- β-D-Allopyranose, 5TMS derivative
- α-D-(+)-Talopyranose, 5TMS derivative
- β-D-(+)-Talopyranose, 5TMS derivative
- α-D-Allopyranose, 5TMS derivative
- Other names: β-D-Glucopyranose, 1,2,3,4,6-pentakis-O-(trimethylsilyl)-; Glucopyranoside, trimethylsilyl 2,3,4,6-tetrakis-O-(trimethylsilyl)-, β-D-; 1,2,3,4,6-Pentakis-O-(trimethylsilyl)-β-D-Glucopyranose; β-D-Glucopyranose, TMS; .beta.-D-(+)-Glucopyranose, pentakis(trimethylsilyl) ether; β-Glucopyranose, TMS; β-Glucose, TMS; Glucopyranose, pentakis-TMS; Glucopyranose, TMS
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Mass spectrum (electron ionization)
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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| Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
|---|---|
| Origin | NIST Mass Spectrometry Data Center, 2010 |
| NIST MS number | 380337 |
Gas Chromatography
Go To: Top, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | Carbowax 20M | 160. | 1972. | Martinez-Castro, Paez, et al., 1989 | Chrompack; Column length: 25. m; Column diameter: 0.22 mm |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | VF-5MS | 1971.3 | Tretyakov, 2011 | 30. m/0.25 mm/0.25 μm, He; Tstart: 60. C; Tend: 270. C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1931. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium, 3. K/min, 300. C @ 30. min; Tstart: 50. C |
| Capillary | HP-5 | 1931. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium, 3. K/min, 300. C @ 30. min; Tstart: 50. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5 | 1930. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
| Capillary | HP-5 | 1930. | Isidorov, Lech, et al., 2008 | 30. m/0.25 mm/0.25 μm, Helium; Program: not specified |
References
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinez-Castro, Paez, et al., 1989
Martinez-Castro, I.; Paez, M.I.; Sanz, J.; Garcia-Raso, A.,
Gas Chromatographic Behaviour of Carbohydrate Trimethylsilyl Ethers. II. Aldohexoses,
J. Chromatogr., 1989, 462, 49-60, https://doi.org/10.1016/S0021-9673(00)91335-9
. [all data]
Tretyakov, 2011
Tretyakov, K.V.,
Retention Data (March 2011). NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2011. [all data]
Isidorov, Lech, et al., 2008
Isidorov, V.A.; Lech, P.; Zolciak, A.; Rusak, N.; Szczepaniak, L.,
Gas Chromatographic - nass spectrometric investigation of metabolites from the needles and roots of pine seedlings at early stages of pathogenic fungi Armillaria ostoyae attack,
Trees, 2008, 22, 4, 531-542, https://doi.org/10.1007/s00468-008-0213-z
. [all data]
Notes
Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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