11-Methyltricosane
- Formula: C24H50
- Molecular weight: 338.6538
- IUPAC Standard InChI: InChI=1S/C24H50/c1-4-6-8-10-12-14-15-17-19-21-23-24(3)22-20-18-16-13-11-9-7-5-2/h24H,4-23H2,1-3H3
- IUPAC Standard InChIKey: XIOFCJYPVMLOKU-UHFFFAOYSA-N
- CAS Registry Number: 27538-41-6
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Tricosane, 11-methyl-; 11-Methyl-n-tricosane
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Gas Chromatography
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Capillary | Apiezon L | 100. | 2332. | Rappoport and Gäumann, 1973 |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-5MS | 2335. | Steinmetz, Schmolz, et al., 2003 | 30. m/0.32 mm/0.25 μm, He, 3. K/min; Tstart: 150. C; Tend: 280. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-5MS | 2333.2 | Andriamaharavo, 2014 | 30. m/0.25 mm/0.25 μm, He; Program: 60C (1 min) => 5 C/min => 210C => 10 C/min => 280C (15 min) |
| Capillary | Methyl Silicone | 2336. | Kaib, Jmhasly, et al., 2004 | Program: 80C(1.5min) =.40C/min => 160C => 2.5C/min => 280C |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | BP-1 | 2336. | Mutis, Parra, et al., 2009 | 30. m/0.22 mm/0.25 μm, Helium, 5. K/min, 290. C @ 15. min; Tstart: 40. C |
| Capillary | BP-1 | 2338. | Mutis, Parra, et al., 2009 | 30. m/0.22 mm/0.25 μm, Helium, 5. K/min, 290. C @ 15. min; Tstart: 40. C |
| Capillary | OV-1 | 2338.2 | Krkosova, Kubinec, et al., 2007 | 100. m/0.32 mm/0.25 μm, Helium, 5. K/min, 310. C @ 5. min; Tstart: 30. C |
| Capillary | Dexsil 300 | 2334. | Lockey, 1978 | 5. K/min; Column length: 15. m; Tstart: 50. C; Tend: 370. C |
| Capillary | Dexsil 300 | 2334. | Lockey, 1978 | 5. K/min; Column length: 15. m; Tstart: 50. C; Tend: 370. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | CP Sil 5 CB | 2337. | Kenig, Sinninghe Damsté, et al., 1995 | 25. m/0.32 mm/0.2 μm, He; Program: 50C => 20C/min => 130C => 4C/min => 300C (20min) |
| Capillary | Squalane | 2333. | Petrov, 1984 | Program: not specified |
References
Go To: Top, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Rappoport and Gäumann, 1973
Rappoport, S.; Gäumann, T.,
114. L'indice de rétention des alcanes isomères en chromatographie en phase gazeuse,
Helv. Chim. Acta, 1973, 56, 3, 1145-1158, https://doi.org/10.1002/hlca.19730560338
. [all data]
Steinmetz, Schmolz, et al., 2003
Steinmetz, I.; Schmolz, E.; Ruther, J.,
Cuticular lipids as trail pheromone in a social wasp,
Proc. R. Soc. London B:, 2003, 270, 1513, 385-391, https://doi.org/10.1098/rspb.2002.2256
. [all data]
Andriamaharavo, 2014
Andriamaharavo, N.R.,
Retention Data. NIST Mass Spectrometry Data Center., NIST Mass Spectrometry Data Center, 2014. [all data]
Kaib, Jmhasly, et al., 2004
Kaib, M.; Jmhasly, P.; Wilfert, L.; Durka, W.; Franke, S.; Francke, W.; Leuthold, R.H.; Brandl, R.,
Cuticular hydrocarbons and aggression in the termite Macrotermes Subhyalinus,
J. Chem. Ecol., 2004, 30, 2, 365-385, https://doi.org/10.1023/B:JOEC.0000017983.89279.c5
. [all data]
Mutis, Parra, et al., 2009
Mutis, A.; Parra, L.; Palma, R.; Pardo, F.; Perich, F.; Quiroz, A.,
Evidence of contact pheromone use in mating behavior of the raspberry weevil (Coleoptera: Corculionidae),
Environ. Entomol., 2009, 38, 1, 192-197, https://doi.org/10.1603/022.038.0124
. [all data]
Krkosova, Kubinec, et al., 2007
Krkosova, Z.; Kubinec, R.; Addova, G.; Jurdakova, H.; Blasko, J.; Ostrovsky, I.; Sojak, L.,
Gas chromatographic - mass spectrometric characterization of monomethylalkanes from fuel diesel,
Petroleum Coal, 2007, 49, 3, 51-62. [all data]
Lockey, 1978
Lockey, K.H.,
The adult cuticular hydrocarbons of Tenebrio Molitor L. and Tenebrio Obscurus F. (Coleoptera: Tenebrionidae),
Insect Biochem., 1978, 8, 4, 237-250, https://doi.org/10.1016/0020-1790(78)90032-X
. [all data]
Kenig, Sinninghe Damsté, et al., 1995
Kenig, F.; Sinninghe Damsté, J.S.; Kock-van Dalen, A.C.; Rijpstra, W.I.C.; Huc, A.Y.; de Leeuw, J.W.,
Occurrence and origin of mono-, di-, and trimethylalkanes in modern and holocene cyanobacterial mats from Abu Dhabi, United Arab Emirates,
Geochim. Cosmochim. Acta, 1995, 59, 14, 2999-3015, https://doi.org/10.1016/0016-7037(95)00190-5
. [all data]
Petrov, 1984
Petrov, A.A.,
Hydrocarbons of petroleum, Nauka (publishing house), Moscow, 1984, 263. [all data]
Notes
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- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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