HSS anion
- Formula: HS2-
- Molecular weight: 65.138
- CAS Registry Number: 26693-74-3
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 1.916 ± 0.015 | N/A | Entfellner and Boesl, 2009 | |
| 1.907 ± 0.023 | LPES | Moran and Ellison, 1988 |
Protonation reactions
HS2- + =
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1447. ± 15. | kJ/mol | D-EA | Entfellner and Boesl, 2009 | gas phase |
| ΔrH° | 1448. ± 13. | kJ/mol | G+TS | Ohair, Depuy, et al., 1993 | gas phase |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1418. ± 15. | kJ/mol | H-TS | Entfellner and Boesl, 2009 | gas phase |
| ΔrG° | 1418. ± 13. | kJ/mol | IMRB | Ohair, Depuy, et al., 1993 | gas phase |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Entfellner and Boesl, 2009
Entfellner, M.; Boesl, U.,
Photodetachment-photoelectron spectroscopy of disulfanide: the ground and first excited electronic state of HS2 and DS2,
Phys. Chem. Chem. Phys., 2009, 11, 15, 2657-2662, https://doi.org/10.1039/b820174a
. [all data]
Moran and Ellison, 1988
Moran, S.; Ellison, G.B.,
Photoelectron Spectroscopy of Sulfur Ions,
J. Phys. Chem., 1988, 92, 7, 1794, https://doi.org/10.1021/j100318a021
. [all data]
Ohair, Depuy, et al., 1993
Ohair, R.A.J.; Depuy, C.H.; Bierbaum, V.M.,
Gas-Phase Chemistry and Thermochemistry of the Hydroxysulfide Anion, HOS-,
J. Phys. Chem., 1993, 97, 30, 7955, https://doi.org/10.1021/j100132a026
. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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