Cr(CO)5


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-644. ± 13.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -908.4 ± 2.6 kJ/mol for the enthalpy of formation of Cr(CO)6(g)
Δfgas-643. ± 21.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -908.4 ± 2.6 kJ/mol for the enthalpy of formation of Cr(CO)6(g)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

View reactions leading to C5CrO5+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
>2.26361IMRBSallans, Lane, et al., 1985 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Sallans, Lane, et al., 1985
Sallans, L.; Lane, K.R.; Squires, R.R.; Freiser, B.S., Generation and reactions of atomic metal anions in the gas phase. Determination of the heterolytic and homolytic bond energies of VH, VrH, FeH, CoH, and MoH, J. Am. Chem. Soc., 1985, 107, 4379. [all data]


Notes

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