Dibutoxymethane
- Formula: C9H20O2
- Molecular weight: 160.2539
- IUPAC Standard InChIKey: QLCJOAMJPCOIDI-UHFFFAOYSA-N
- CAS Registry Number: 2568-90-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Di-n-butoxymethane; Methane, dibutoxy-; Butane, 1,1'-[methylenebis(oxy)]bis-; Butylal; Dibutyl formal; Formaldehyde dibutyl acetal; Di-n-butyl formal; NSC 241; 1,1'-[methylenebis(oxy)]dibutane
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Gas phase thermochemistry data
Go To: Top, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -119.8 ± 0.8 | kcal/mol | Ccb | Skuratov, Strepikheev, et al., 1957 | Heat of formation derived by Cox and Pilcher, 1970 |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 455.0 | K | N/A | Timmermans, 1927 | Uncertainty assigned by TRC = 0.6 K; source of data not clear; TRC |
Tboil | 452.6 | K | N/A | Timmermans, 1922 | Uncertainty assigned by TRC = 0.4 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 214. | K | N/A | Timmermans, 1927 | Uncertainty assigned by TRC = 0.3 K; TRC |
Tfus | 215.05 | K | N/A | Timmermans, 1922 | Uncertainty assigned by TRC = 0.4 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 11.5 | kcal/mol | EB | Palczewska-Tulinska and Szafranski, 2000 | Based on data from 363. to 452. K.; AC |
ΔvapH° | 11.5 ± 0.6 | kcal/mol | E | Skuratov, Strepikheev, et al., 1957 | Heat of formation derived by Cox and Pilcher, 1970; ALS |
ΔvapH° | 11.5 | kcal/mol | N/A | Skuratov, Strepikheev, et al., 1957 | DRB |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
11.4 | 381. | EB | Palczewska-Tulinska and Szafranski, 2000 | Based on data from 366. to 452. K.; AC |
13.7 | 293. | V | Skuratov, Strepikheev, et al., 1957 | Combustion for liq at 293 K; ALS |
Mass spectrum (electron ionization)
Go To: Top, Gas phase thermochemistry data, Phase change data, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 5718 |
Gas Chromatography
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
Column type | Active phase | Temperature (C) | I | Reference | Comment |
---|---|---|---|---|---|
Packed | Apiezon L | 120. | 1020. | Bogoslovsky, Anvaer, et al., 1978 | Celite 545 |
Packed | Apiezon L | 160. | 1036. | Bogoslovsky, Anvaer, et al., 1978 | Celite 545 |
References
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Skuratov, Strepikheev, et al., 1957
Skuratov, S.M.; Strepikheev, A.A.; Shtekhter, S.M.; Volokhina, A.V.,
About the enthalpies of polymerization of cyclic formales,
Dokl. Akad. Nauk SSSR, 1957, 117, 263-265. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Timmermans, 1927
Timmermans, J.,
The Melting Point of Organic Substances,
Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]
Timmermans, 1922
Timmermans, J.,
Investigation of the Freezing Point of Organic Substances VII,
Bull. Soc. Chim. Belg., 1922, 31, 389. [all data]
Palczewska-Tulinska and Szafranski, 2000
Palczewska-Tulinska, Marcela; Szafranski, Andrzej M.,
Selected Physicochemical Properties of Dibutoxymethane,
J. Chem. Eng. Data, 2000, 45, 6, 988-990, https://doi.org/10.1021/je000070l
. [all data]
Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S.,
Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔfH°gas Enthalpy of formation of gas at standard conditions ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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