Dibutoxymethane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-501. ± 3.kJ/molCcbSkuratov, Strepikheev, et al., 1957Heat of formation derived by Cox and Pilcher, 1970

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.

Quantity Value Units Method Reference Comment
Tboil455.0KN/ATimmermans, 1927Uncertainty assigned by TRC = 0.6 K; source of data not clear; TRC
Tboil452.6KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Tfus214.KN/ATimmermans, 1927Uncertainty assigned by TRC = 0.3 K; TRC
Tfus215.05KN/ATimmermans, 1922Uncertainty assigned by TRC = 0.4 K; TRC
Quantity Value Units Method Reference Comment
Δvap48.1kJ/molEBPalczewska-Tulinska and Szafranski, 2000Based on data from 363. to 452. K.; AC
Δvap48. ± 3.kJ/molESkuratov, Strepikheev, et al., 1957Heat of formation derived by Cox and Pilcher, 1970; ALS
Δvap48.0kJ/molN/ASkuratov, Strepikheev, et al., 1957DRB

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
47.9381.EBPalczewska-Tulinska and Szafranski, 2000Based on data from 366. to 452. K.; AC
57.3293.VSkuratov, Strepikheev, et al., 1957Combustion for liq at 293 K; ALS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedApiezon L120.1020.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L160.1036.Bogoslovsky, Anvaer, et al., 1978Celite 545

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Skuratov, Strepikheev, et al., 1957
Skuratov, S.M.; Strepikheev, A.A.; Shtekhter, S.M.; Volokhina, A.V., About the enthalpies of polymerization of cyclic formales, Dokl. Akad. Nauk SSSR, 1957, 117, 263-265. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Timmermans, 1927
Timmermans, J., The Melting Point of Organic Substances, Bull. Soc. Chim. Belg., 1927, 36, 502. [all data]

Timmermans, 1922
Timmermans, J., Investigation of the Freezing Point of Organic Substances VII, Bull. Soc. Chim. Belg., 1922, 31, 389. [all data]

Palczewska-Tulinska and Szafranski, 2000
Palczewska-Tulinska, Marcela; Szafranski, Andrzej M., Selected Physicochemical Properties of Dibutoxymethane, J. Chem. Eng. Data, 2000, 45, 6, 988-990, https://doi.org/10.1021/je000070l . [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]


Notes

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