Dipotassium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas29.560kcal/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
gas,1 bar59.682cal/mol*KReviewChase, 1998Data last reviewed in December, 1983

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1300.1300. to 6000.
A 5.4155817.412359
B 12.80000-1.382941
C -13.462400.276767
D 3.826100-0.018846
E 0.0835362.970591
F 27.7701032.06570
G 63.4530173.42949
H 29.5609929.56099
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1983 Data last reviewed in December, 1983

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

K8+ + Dipotassium = (K8+ • Dipotassium)

By formula: K8+ + K2 = (K8+ • K2)

Quantity Value Units Method Reference Comment
Δr20.3kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K9+ + Dipotassium = (K9+ • Dipotassium)

By formula: K9+ + K2 = (K9+ • K2)

Quantity Value Units Method Reference Comment
Δr12.7kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K11+ + Dipotassium = (K11+ • Dipotassium)

By formula: K11+ + K2 = (K11+ • K2)

Quantity Value Units Method Reference Comment
Δr15.7kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K13+ + Dipotassium = (K13+ • Dipotassium)

By formula: K13+ + K2 = (K13+ • K2)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K3+ + Dipotassium = (K3+ • Dipotassium)

By formula: K3+ + K2 = (K3+ • K2)

Quantity Value Units Method Reference Comment
Δr15.9kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K4+ + Dipotassium = (K4+ • Dipotassium)

By formula: K4+ + K2 = (K4+ • K2)

Quantity Value Units Method Reference Comment
Δr13.8kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K6+ + Dipotassium = (K6+ • Dipotassium)

By formula: K6+ + K2 = (K6+ • K2)

Quantity Value Units Method Reference Comment
Δr19.1kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K5+ + Dipotassium = (K5+ • Dipotassium)

By formula: K5+ + K2 = (K5+ • K2)

Quantity Value Units Method Reference Comment
Δr18.2kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K7+ + Dipotassium = (K7+ • Dipotassium)

By formula: K7+ + K2 = (K7+ • K2)

Quantity Value Units Method Reference Comment
Δr21.7kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K10+ + Dipotassium = (K10+ • Dipotassium)

By formula: K10+ + K2 = (K10+ • K2)

Quantity Value Units Method Reference Comment
Δr14.1kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

K12+ + Dipotassium = (K12+ • Dipotassium)

By formula: K12+ + K2 = (K12+ • K2)

Quantity Value Units Method Reference Comment
Δr16.4kcal/molPDissBrechignac, Cahuzac, et al., 1990gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Brechignac, Cahuzac, et al., 1990
Brechignac, C.; Cahuzac, P.; Carlier, F.; De Frutos, M.; Leyniger, J., Cohesive Energies of (K)n+ 5<n<200 from Photoevaporation Experiments, J. Chem. Phys., 1990, 93, 10, 7449, https://doi.org/10.1063/1.459418 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References