Disodium


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas33.956kcal/molReviewChase, 1998Data last reviewed in December, 1983
Quantity Value Units Method Reference Comment
gas,1 bar55.031cal/mol*KReviewChase, 1998Data last reviewed in December, 1983

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1400.1400. to 2800.2800. to 6000.
A 8.57356222.23530-118.2720
B 0.987445-10.5207055.28989
C 0.7393191.798310-8.050161
D -0.9090110.0720350.382342
E 0.006706-4.515510204.8050
F 31.3732118.38250295.8819
G 65.1238173.5485983.63401
H 33.9555933.9555933.95559
ReferenceChase, 1998Chase, 1998Chase, 1998
Comment Data last reviewed in December, 1983 Data last reviewed in December, 1983 Data last reviewed in December, 1983

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Na7+ + Disodium = (Na7+ • Disodium)

By formula: Na7+ + Na2 = (Na7+ • Na2)

Quantity Value Units Method Reference Comment
Δr30.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na9+ + Disodium = (Na9+ • Disodium)

By formula: Na9+ + Na2 = (Na9+ • Na2)

Quantity Value Units Method Reference Comment
Δr13.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na11+ + Disodium = (Na11+ • Disodium)

By formula: Na11+ + Na2 = (Na11+ • Na2)

Quantity Value Units Method Reference Comment
Δr19.4kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na13+ + Disodium = (Na13+ • Disodium)

By formula: Na13+ + Na2 = (Na13+ • Na2)

Quantity Value Units Method Reference Comment
Δr18.7kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na3+ + Disodium = (Na3+ • Disodium)

By formula: Na3+ + Na2 = (Na3+ • Na2)

Quantity Value Units Method Reference Comment
Δr17.1kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na5+ + Disodium = (Na5+ • Disodium)

By formula: Na5+ + Na2 = (Na5+ • Na2)

Quantity Value Units Method Reference Comment
Δr21.9kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Na3+ + Disodium = (Na3+ • Disodium)

By formula: Na3+ + Na2 = (Na3+ • Na2)

Quantity Value Units Method Reference Comment
Δr17.1kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na5+ + Disodium = (Na5+ • Disodium)

By formula: Na5+ + Na2 = (Na5+ • Na2)

Quantity Value Units Method Reference Comment
Δr21.9kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na7+ + Disodium = (Na7+ • Disodium)

By formula: Na7+ + Na2 = (Na7+ • Na2)

Quantity Value Units Method Reference Comment
Δr30.2kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na9+ + Disodium = (Na9+ • Disodium)

By formula: Na9+ + Na2 = (Na9+ • Na2)

Quantity Value Units Method Reference Comment
Δr13.8kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na11+ + Disodium = (Na11+ • Disodium)

By formula: Na11+ + Na2 = (Na11+ • Na2)

Quantity Value Units Method Reference Comment
Δr19.4kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

Na13+ + Disodium = (Na13+ • Disodium)

By formula: Na13+ + Na2 = (Na13+ • Na2)

Quantity Value Units Method Reference Comment
Δr18.7kcal/molPDissBrechignac, Cahuzac, et al., 1989gas phase

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Brechignac, Cahuzac, et al., 1989
Brechignac, C.; Cahuzac, P.; Leygnier, J.; Pfalum, R.; Roux, J.P.; Weiner, J., Stability of Alkali Cluster Ions, Z. Phys. D: At. Mol. Clusters, 1989, 12, 1-4, 199, https://doi.org/10.1007/BF01426937 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Ion clustering data, References