Methyldinitramine
- Formula: CH3N3O4
- Molecular weight: 121.0522
- IUPAC Standard InChIKey: AAIWMHUUYNFKAM-UHFFFAOYSA-N
- CAS Registry Number: 25346-05-8
- Chemical structure:
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 43.1 ± 6.3 | kJ/mol | Eqk | Korsunskii, Sitonina, et al., 1989 | see 87 MIR/KOR |
ΔfH°gas | 53.5 ± 0.8 | kJ/mol | Ccr | Miroshnichenko, Korchatova, et al., 1987 |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | 1.7 ± 0.8 | kJ/mol | Eqk | Korsunskii, Sitonina, et al., 1989 | see 87 MIR/KOR |
Quantity | Value | Units | Method | Reference | Comment |
ΔfH°solid | 1.5 ± 0.7 | kJ/mol | Ccr | Miroshnichenko, Korchatova, et al., 1987 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -823.8 ± 0.7 | kJ/mol | Ccr | Miroshnichenko, Korchatova, et al., 1987 |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 41.4 ± 5.4 | kJ/mol | V | Korsunskii, Sitonina, et al., 1989 | see 87 MIR/KOR |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 52.0 ± 0.4 | kJ/mol | C | Miroshnichenko, Korchatova, et al., 1987 |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, NIST Free Links, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Korsunskii, Sitonina, et al., 1989
Korsunskii, B.L.; Sitonina, G.V.; Fedorov, B.S.; Dubovitskii, F.I.; Eremenko, L.T.,
Kinetics of the thermal decomposition of N,N-(Dinitro)alkylamines,
Bull. Acad. Sci. USSR, Div. Chem. Sci., 1989, 710-713. [all data]
Miroshnichenko, Korchatova, et al., 1987
Miroshnichenko, E.A.; Korchatova, L.I.; Korsunskii, B.L.; Fedorov, B.S.; Orlov, Yu.D.; Eremenko, L.T.; Lebedev, Yu.A.; Dubovitskii, F.I.,
Thermochemistry of methyldinitramine and the enthalpy of formation of the methylnitramine radical,
Dokl. Akad. Nauk SSSR, 1987, 295, 419-423. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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