Chlorine dioxide anion
- Formula: ClO2-
- Molecular weight: 67.452
- CAS Registry Number: 25052-55-5
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
Electron affinity of neutral species
| EAneutral (eV) | Method | Reference | Comment |
|---|---|---|---|
| 2.150 ± 0.020 | ZEKE | Tschurl and Boesl, 2007 | Vertical Detachment Energy: 2.39±0.02 eV |
| 2.1451 ± 0.0025 | ZEKE | Distelrath and Boesl, 2000 | Reassignment of bands from Gilles, Polak, et al., 1992 |
| 2.150 ± 0.030 | LPES | Wang and Wang, 2000 | Vertical Detachment Energy: 2.38±0.05 eV |
| 2.3780 ± 0.0060 | LPES | Gilles, Polak, et al., 1992 | |
| 2.37 ± 0.10 | IMRB | Babcock, Pentecost, et al., 1989 | EA: Less than NO2, greater than HS., SF4 |
| <2.16821 | ECD | Wecker, Christodoulides, et al., 1981 | |
| 1.76 ± 0.16 | EIAE | Baluev, Nikitin, et al., 1980 | From FClO3 |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Tschurl and Boesl, 2007
Tschurl, M.; Boesl, U.,
Photodetachment photoelectron spectroscopy of the weakly bound OClO-center dot H2O complex,
Z. Phys. Chem., 2007, 221, 5, 609-618, https://doi.org/10.1524/zpch.2007.221.5.609
. [all data]
Distelrath and Boesl, 2000
Distelrath, V.; Boesl, U.,
Mass selective gas phase study of ClO, OClO, ClOO and ClAr by anion-ZEKE-photoelectron spectroscopy,
Faraday Disc. Chem. Soc., 2000, 115, 161-174, https://doi.org/10.1039/a909618c
. [all data]
Gilles, Polak, et al., 1992
Gilles, M.K.; Polak, M.L.; Lineberger, W.C.,
Photoelectron Spectroscopy of the Halogen Oxide Anions FO-, ClO-, BrO-, IO-, OClO-, and OIO-,
J. Chem. Phys., 1992, 96, 11, 8012, https://doi.org/10.1063/1.462352
. [all data]
Wang and Wang, 2000
Wang, X.B.; Wang, L.S.,
The electronic structure and electron affinities of higher chlorine oxide radicals ClOx (x=2-4) from photoelectron spectroscopy of ClOx- anions,
J. Chem. Phys., 2000, 113, 24, 10928-10933, https://doi.org/10.1063/1.1326067
. [all data]
Babcock, Pentecost, et al., 1989
Babcock, L.M.; Pentecost, T.; Koppenol, W.H.,
Electron Affinity of Chlorine Dioxide,
J. Phys. Chem., 1989, 93, 25, 8126, https://doi.org/10.1021/j100362a002
. [all data]
Wecker, Christodoulides, et al., 1981
Wecker, D.; Christodoulides, A.A.; Schnidler, R.N.,
Studies by the Electron Cyclotron Resonance (ECR) Technique. XV. Interactions of Thermal-Energy Electrons with ClO2 and Cl2O,
Int. J. Mass Spectrom. Ion Phys., 1981, 38, 2-3, 291, https://doi.org/10.1016/0020-7381(81)80084-8
. [all data]
Baluev, Nikitin, et al., 1980
Baluev, A.V.; Nikitin, I.M.; Fedorova, L.I.; Rossolovskii, V.Ya.,
Mass Spectrometric Study of Chlorine Pentafluoride Ionization by Electron Impact, Izv. Akad. Nauk SSR Ser. Khim. 487, 1980. [all data]
Notes
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- Symbols used in this document:
EAneutral Electron affinity of neutral species - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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