cis,Cics-2,5-di-tert-butylcyclohexanol


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

cis,Cics-2,5-di-tert-butylcyclohexanol = Cyclohexanol, 2,5-di-tert-butyl-, cis-1,2, trans-1,5

By formula: C14H28O = C14H28O

Quantity Value Units Method Reference Comment
Δr-27.9 ± 1.5kJ/molCmPasto and Rao, 1970liquid phase; solvent: CCl4

cis,Cics-2,5-di-tert-butylcyclohexanol = trans,trans-2,5-Di-tert-butylcyclohexanol

By formula: C14H28O = C14H28O

Quantity Value Units Method Reference Comment
Δr-28.3 ± 1.1kJ/molCmPasto and Rao, 1970liquid phase; solvent: CCl4

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pasto and Rao, 1970
Pasto, D.J.; Rao, D.R., Thermodynamic, conformational, and chemical reactivity studies of the 2,5-di-tert-butylcyclohexyl system. Reversal of the thermodynamic stability with chemical reactivity trends of cyclohexyl derivatives, J. Am. Chem. Soc., 1970, 92, 5151-5160. [all data]


Notes

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