ethyliodomercury


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas14.3 ± 4.1kJ/molReviewMartinho SimõesThe enthalpy of formation relies on 30.2 ± 1.5 kJ/mol for the enthalpy of formation of Hg(Et)2(l).

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-65.2 ± 2.9kJ/molReviewMartinho SimõesThe enthalpy of formation relies on 30.2 ± 1.5 kJ/mol for the enthalpy of formation of Hg(Et)2(l).

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub79.5 ± 2.9kJ/molRSCCharnley and Skinner, 1951MS

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
79.7 ± 2.9294.5VStephenson and Malanowski, 1987Based on data from 286. to 303. K. See also Pilcher and Skinner, 1983, Hartley, Pritchard, et al., 1951, and Charnley and Skinner, 1951, 2.; AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Charnley and Skinner, 1951
Charnley, T.; Skinner, H.A., J. Chem. Soc., 1951, 1921.. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Hartley, Pritchard, et al., 1951
Hartley, K.; Pritchard, H.O.; Skinner, H.A., Thermochemistry of metallic alkyls. IV. Mercury diethyl and mercury diphenyl, Trans. Faraday Soc., 1951, 47, 254, https://doi.org/10.1039/tf9514700254 . [all data]

Charnley and Skinner, 1951, 2
Charnley, T.; Skinner, H.A., 424. Measurements of the vapour pressures of some alkylmercury halides. The latent heats of sublimation of methyl- and ethyl- mercury halides, J. Chem. Soc., 1951, 1921, https://doi.org/10.1039/jr9510001921 . [all data]


Notes

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