N,N-Dimethylpivalamide
- Formula: C7H15NO
- Molecular weight: 129.2001
- IUPAC Standard InChI: InChI=1S/C7H15NO/c1-7(2,3)6(9)8(4)5/h1-5H3
- IUPAC Standard InChIKey: RLVGHTRVYWUWSH-UHFFFAOYSA-N
- CAS Registry Number: 24331-71-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: N,N,2,2-Tetramethylpropionamide; N,N,2,2-Tetramethylpropanamide; 2,2-Dimethylpropionic acid dimethylamide; N,N-Dimethyl-tert-butylcarboxamide
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | -341.2 ± 2.1 | kJ/mol | Ccb | Abboud, Jimenez, et al., 1995 | |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -4557.1 ± 1.9 | kJ/mol | Ccb | Abboud, Jimenez, et al., 1995 |
Gas Chromatography
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | SE-30 | 180. | 1023. | Oszczapowicz, Ciszkowski, et al., 1986 | N2, Chromosorb W AW; Column length: 3. m |
References
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Abboud, Jimenez, et al., 1995
Abboud, J.-L.M.; Jimenez, P.; Roux, M.V.; Turrion, C.; Lopez-Mardomingo, C.; Podosenin, A.; Rogers, D.W.; Liebman, J.F.,
Interrelations of the energetics of amides and alkenes: enthalpies of formation of N,N-dimethyl dertivatives of pivalamide, 1-adamantylcarboxamide and benzamide, and of styrene and its a-, trans-β- and β,β-methylated derivates,
J. Phys. Org. Chem., 1995, 8, 15-25. [all data]
Oszczapowicz, Ciszkowski, et al., 1986
Oszczapowicz, J.; Ciszkowski, K.; Osek, J.,
Amidines. XXVI. Retention indices of N1,N1-dimethylpropionamidines, isobutyramidines, pivalamidines and phenylacetamidines on a non-polar column,
J. Chromatogr., 1986, 362, 383-389, https://doi.org/10.1016/S0021-9673(01)86990-9
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Gas Chromatography, References
- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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