Tetradecane, 1-chloro-
- Formula: C14H29Cl
- Molecular weight: 232.833
- IUPAC Standard InChIKey: RNHWYOLIEJIAMV-UHFFFAOYSA-N
- CAS Registry Number: 2425-54-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Myristyl chloride; Tetradecyl chloride; 1-Chlorotetradecane; n-Tetradecyl chloride
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 20.7 | kcal/mol | N/A | Bolotnikov and Neruchev, 2006 | AC |
Reduced pressure boiling point
Tboil (K) | Pressure (atm) | Reference | Comment |
---|---|---|---|
413.7 | 0.005 | Aldrich Chemical Company Inc., 1990 | BS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
16.4 | 429. | A,DTA | Stephenson and Malanowski, 1987 | Based on data from 414. to 570. K. See also Kemme and Kreps, 1969.; AC |
19.2 | 313. | GC | Jönsson, Mathiasson, et al., 1980 | Based on data from 313. to 373. K.; AC |
18.6 | 333. | GC | Jönsson, Mathiasson, et al., 1980 | Based on data from 313. to 373. K.; AC |
17.8 | 353. | GC | Jönsson, Mathiasson, et al., 1980 | Based on data from 313. to 373. K.; AC |
17.4 | 373. | GC | Jönsson, Mathiasson, et al., 1980 | Based on data from 313. to 373. K.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference |
---|---|---|---|---|
414.9 to 570. | 4.00636 | 1776.491 | -126.97 | Kemme and Kreps, 1969 |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bolotnikov and Neruchev, 2006
Bolotnikov, M.F.; Neruchev, Yu.A.,
The enthalpies of vaporization and intermolecular interaction energies of 1-chloroalkanes,
Russ. J. Phys. Chem., 2006, 80, 8, 1191-1197, https://doi.org/10.1134/S0036024406080024
. [all data]
Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc.,
Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kemme and Kreps, 1969
Kemme, Herbert R.; Kreps, Saul I.,
Vapor pressure of primary n-alkyl chlorides and alcohols,
J. Chem. Eng. Data, 1969, 14, 1, 98-102, https://doi.org/10.1021/je60040a011
. [all data]
Jönsson, Mathiasson, et al., 1980
Jönsson, Jan Åke; Mathiasson, Lennart; Olsson, Anne-Marie; Tuhtar, Dinko; Sjöblom, Johan; Strand, T.G.; Sukhoverkhov, V.F.,
A GLC Method for the Determination of Low Vapour Pressures Applied to 1-Chloroalkanes.,
Acta Chem. Scand., 1980, 34a, 147-150, https://doi.org/10.3891/acta.chem.scand.34a-0147
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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