Xenon cation


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(Xe+ • Xenon) + Xenon = (Xe+ • 2Xenon)

By formula: (Xe+ • Xe) + Xe = (Xe+ • 2Xe)

Quantity Value Units Method Reference Comment
Δr6.8kcal/molDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986
Δr6.75kcal/molDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986
Quantity Value Units Method Reference Comment
Δr18.7cal/mol*KDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986
Δr18.7cal/mol*KDTHelm, 1976gas phase; corrected for ln T by Keesee and Castleman, 1986

Xe+ + Xenon = (Xe+ • Xenon)

By formula: Xe+ + Xe = (Xe+ • Xe)

Quantity Value Units Method Reference Comment
Δr23.8kcal/molPINg, Trevor, et al., 1976gas phase
Δr22.8kcal/molSCATTERINGMittman and Weise, 1974gas phase
Δr22.4kcal/molSCATTERINGLorentz, Olson, et al., 1973gas phase
Δr22.8kcal/molPISamson, 1966gas phase

Xe+ + Argon = (Xe+ • Argon)

By formula: Xe+ + Ar = (Xe+ • Ar)

Quantity Value Units Method Reference Comment
Δr4.1kcal/molPIDehmer and Pratt, 1982gas phase
Δr6.0kcal/molSIFTJones, Lister, et al., 1980gas phase
Δr3.2kcal/molPINg, Tiedemann, et al., 1977gas phase
Quantity Value Units Method Reference Comment
Δr19.4cal/mol*KSIFTJones, Lister, et al., 1980gas phase

(Xe+ • 2Xenon) + Xenon = (Xe+ • 3Xenon)

By formula: (Xe+ • 2Xe) + Xe = (Xe+ • 3Xe)

Quantity Value Units Method Reference Comment
Δr6.03 ± 0.15kcal/molPHPMSHiraoka and Mori, 1990gas phase
Quantity Value Units Method Reference Comment
Δr15.1cal/mol*KPHPMSHiraoka and Mori, 1990gas phase

(Xe+ • 3Xenon) + Xenon = (Xe+ • 4Xenon)

By formula: (Xe+ • 3Xe) + Xe = (Xe+ • 4Xe)

Quantity Value Units Method Reference Comment
Δr2.64 ± 0.15kcal/molPHPMSHiraoka and Mori, 1990gas phase
Quantity Value Units Method Reference Comment
Δr13.1cal/mol*KPHPMSHiraoka and Mori, 1990gas phase

Xe+ + Krypton = (Xe+ • Krypton)

By formula: Xe+ + Kr = (Xe+ • Kr)

Quantity Value Units Method Reference Comment
Δr8.9kcal/molPIDehmer and Pratt, 1982gas phase
Δr8.5kcal/molPINg, Tiedemann, et al., 1977gas phase

Xe+ + neon = (Xe+ • neon)

By formula: Xe+ + Ne = (Xe+ • Ne)

Quantity Value Units Method Reference Comment
Δr0.95kcal/molPIDehmer and Pratt, 1982gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Helm, 1976
Helm, H., Formation of Xe3+ Ions in Xenon at Temperatures Between 210 and 293 K, Phys. Rev. A, 1976, 14, 2, 680, https://doi.org/10.1103/PhysRevA.14.680 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Ng, Trevor, et al., 1976
Ng, C.Y.; Trevor, D.J.; Mahan, B.H.; Lee, Y.T., Photoionization Study of the Xe2 van der Waals Molecule, J. Chem. Phys., 1976, 65, 10, 4327, https://doi.org/10.1063/1.432849 . [all data]

Mittman and Weise, 1974
Mittman, H.U.; Weise, H.P., Scattering of Ions V. Elastic Scattering of the Symmetric Rare Gas Ion - Rare Gas Atom Systems, Z. Naturforsch., 1974, A29, 400. [all data]

Lorentz, Olson, et al., 1973
Lorentz, D.C.; Olson, R.E.; Conklin, G.M., Rainbow Scattering for Ar+ + Ar and Xe+ + Xe, Chem. Phys. Lett., 1973, 20, 6, 589, https://doi.org/10.1016/0009-2614(73)80508-1 . [all data]

Samson, 1966
Samson, J.A.R., Ionization Potential of Molecular Xenon and Krypton, J. Opt. Soc. Am., 1966, 56, 8, 1140, https://doi.org/10.1364/JOSA.56.001140 . [all data]

Dehmer and Pratt, 1982
Dehmer, P.M.; Pratt, S.T., Photoionization of ArKr, ArXe, and KrXe and bond dissociation energies of the rare gas dimer ions, J. Chem. Phys., 1982, 77, 4804. [all data]

Jones, Lister, et al., 1980
Jones, J.D.C.; Lister, D.G.; Twiddy, N.D., Equilibrium Constant for the Reaction Xe+ + 2Ar ---> XeAr+ + Ar in the Temperature Range 150 - 300 K and the Dissociation Energy of XeAr+, Chem. Phys. Lett., 1980, 70, 3, 575, https://doi.org/10.1016/0009-2614(80)80128-X . [all data]

Ng, Tiedemann, et al., 1977
Ng, C.Y.; Tiedemann, P.W.; Mahan, B.H.; Lee, Y.T., Photoionization Studies of the Diatomic Internuclear Rare Gas Molecules XeKr, XeAr, and KrAr, J. Chem. Phys., 1977, 66, 12, 5737, https://doi.org/10.1063/1.433848 . [all data]

Hiraoka and Mori, 1990
Hiraoka, K.; Mori, T., Stability of Rare - Gas Cluster Ions, J. Chem. Phys., 1990, 92, 7, 4408, https://doi.org/10.1063/1.457751 . [all data]


Notes

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