Cyclopropane, propyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-3770.kJ/molCcbSlabey and Wise, 1952Corresponding Δfliquid = -310. kJ/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil342.30KN/AGragson, Greenlee, et al., 1955Uncertainty assigned by TRC = 0.5 K
Tboil342.65KN/APines, Huntsman, et al., 1953Uncertainty assigned by TRC = 1.5 K
Tboil341.65KN/ABoeseken and Takes, 1937Uncertainty assigned by TRC = 1. K

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Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin D.HENNEBERG, MAX-PLANCK INSTITUTE, MULHEIM, WEST GERMANY
NIST MS number 60624

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Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedSqualane20.609.Bogoslovsky, Anvaer, et al., 1978 
PackedSqualane80.615.Bogoslovsky, Anvaer, et al., 1978 
CapillarySqualane120.608.9Schomburg and Dielmann, 1973Column length: 100. m; Column diameter: 0.25 mm
CapillarySqualane80.614.8Schomburg and Dielmann, 1973Column length: 100. m; Column diameter: 0.25 mm

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySqualane609.Chen, 2008Program: not specified

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Slabey and Wise, 1952
Slabey, V.A.; Wise, P.H., Hydrogenation of 2-cyclopropyl-1- and -2-alkenes. Isolation and Purification of 2-cyclopropylalkanes, J. Am. Chem. Soc., 1952, 74, 3887-3889. [all data]

Gragson, Greenlee, et al., 1955
Gragson, J.T.; Greenlee, K.W.; Derfer, J.M.; Boord, C.E., Cyclopropane Hydrocarbons from γ-Bromo Ethers, J. Org. Chem., 1955, 20, 275. [all data]

Pines, Huntsman, et al., 1953
Pines, H.; Huntsman, W.D.; Ipatieff, V.N., J. Am. Chem. Soc., 1953, 75, 2311-5. [all data]

Boeseken and Takes, 1937
Boeseken, J.; Takes, H.V., The dielectric moment of a monosubstituted derivattive of cyclopropane (propylcyclopropane)., Recl. Trav. Chim. Pays-Bas, 1937, 56, 858. [all data]

Bogoslovsky, Anvaer, et al., 1978
Bogoslovsky, Yu.N.; Anvaer, B.I.; Vigdergauz, M.S., Chromatographic constants in gas chromatography (in Russian), Standards Publ. House, Moscow, 1978, 192. [all data]

Schomburg and Dielmann, 1973
Schomburg, G.; Dielmann, G., Use of retention increments for identification and correlation of saturated and unsaturated cyclopropane hydrocarbons by means of Kovats indices, Anal. Chem., 1973, 45, 9, 1647-1658, https://doi.org/10.1021/ac60331a021 . [all data]

Chen, 2008
Chen, H.-F., Quantitative prediction of gas chromatography retention indices with support vector machines, radial basis neutral networks and multiple linear regression, Anal. Chim. Acta, 2008, 609, 1, 24-36, https://doi.org/10.1016/j.aca.2008.01.003 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Gas Chromatography, References