2-Buten-1-one, 1-(2,6,6-trimethyl-1,3-cyclohexadien-1-yl)-, (E)-


Van Den Dool and Kratz RI, non-polar column, temperature ramp

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5DB-5HP-5MSDB-5MSDB-5MS
Column length (m) 25.30.30.30.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.50.250.25
Tstart (C) 60.60.35.35.35.
Tend (C) 240.240.225.225.225.
Heat rate (K/min) 4.3.4.10.10.
Initial hold (min) 2. 5.5.5.
Final hold (min)   30.25.25.
I 1385.1381.1384.1390.1397.
ReferenceDehghan, Solaimanian, et al., 2007Flamini, Cioni, et al., 2007Jarunrattanasri, Theerakulkait, et al., 2007Lozano P.R., Drake M., et al., 2007Lozano P.R., Drake M., et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5RTX-1RTX-1DB-5ZB-5
Column length (m) 30.60.60.30.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.320.220.220.320.32
Phase thickness (μm) 0.50.250.250.50.5
Tstart (C) 40.60.60.40.40.
Tend (C) 265.230.230.265.265.
Heat rate (K/min) 7.2.2.7.7.
Initial hold (min)      
Final hold (min) 5.30.35.5.5.
I 1391.1361.1362.1383.1390.
ReferenceMahattanatawee K., Perez-Cacho P.R., et al., 2007Muselli, Rossi, et al., 2007Paolini, Muselli, et al., 2007Ruiz Perez-Cacho, Mahattanatawee, et al., 2007Ruiz Perez-Cacho, Mahattanatawee, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSDB-5RTX-5DB-5HP-5MS
Column length (m) 30.30.10.30.30.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.250.320.180.320.25
Phase thickness (μm) 0.250.240.20.250.25
Tstart (C) 60.40.40.40.80.
Tend (C) 280.240.275.240.300.
Heat rate (K/min) 4.6.50.6.4.
Initial hold (min) 5.2.0.52. 
Final hold (min)  10.0.510. 
I 1381.1385.1394.1389.1388.4
ReferenceSaroglou, Arfan, et al., 2007Scheidig, Czerny, et al., 2007Setkova, Risticevic, et al., 2007Steinhaus and Schieberle, 2007Zeng, Zhao, et al., 2007
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5HP-5MSCP Sil 8 CBDB-1HP-5
Column length (m) 30.30.50.30.25.
Carrier gas N2He HeHe
Substrate      
Column diameter (mm) 0.320.250.320.250.25
Phase thickness (μm) 0.250.25 0.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 240.280.220.240.240.
Heat rate (K/min) 3.3.4.4.4.
Initial hold (min) 3. 5.  
Final hold (min) 5. 30.  
I 1380.1386.1381.1394.1386.
ReferenceDob, Dahmane, et al., 2006Kukic J., Petrovic S., et al., 2006Mahadevan and Farmer, 2006Rezazadeh, Hamedani, et al., 2006Rezazadeh, Hamedani, et al., 2006
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5MSHP-5DB-5HP-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeHeN2N2He
Substrate      
Column diameter (mm) 0.250.250.320.250.25
Phase thickness (μm) 0.250.251.0.250.25
Tstart (C) 60.60.40.60.50.
Tend (C) 280.250.230.220.250.
Heat rate (K/min) 4.10.4.5.4.
Initial hold (min) 5.2.2.10.5.
Final hold (min)  10.10. 15.
I 1381.1385.1378.1382.1383.
ReferenceSaroglou, Dorizas, et al., 2006Zhao J.Y., Liu J.M., et al., 2006Fang and Qian, 2005Flamini, Luigi Cioni, et al., 2005Mahattanatawee, Goodner, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5ZB-5RTX-1HP-5MS
Column length (m) 30.30.30.60.30.
Carrier gas HeHeHeHeHe
Substrate      
Column diameter (mm) 0.250.250.320.220.25
Phase thickness (μm) 0.250.250.50.250.25
Tstart (C) 50.50.40.60.60.
Tend (C) 250.250.265.230.250.
Heat rate (K/min) 4.4.7.2.4.
Initial hold (min) 5.5.  2.
Final hold (min) 15.15.5.35.20.
I 1381.1386.1383.1362.1381.
ReferenceMahattanatawee, Goodner, et al., 2005Mahattanatawee, Goodner, et al., 2005Mahattanatawee, Rouseff, et al., 2005Paolini, Costa, et al., 2005Pino, Mesa, et al., 2005
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase ZB-5HP-5SPB-5SPB-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas HeliumN2HeHeN2
Substrate      
Column diameter (mm) 0.320.250.250.530.25
Phase thickness (μm) 0.500.250.251.50.25
Tstart (C) 40.60.60.100.60.
Tend (C) 265.220.250.250.220.
Heat rate (K/min) 7.5.4.5.5.
Initial hold (min)  10.2. 10.
Final hold (min) 5. 20.  
I 1393.1380.1380.1404.1381.
ReferenceBell, 2004Bertoli, Menichini, et al., 2004Pino, Marbot, et al., 2004Rodríguez-Burruezo, Kollmannsberger, et al., 2004Campeol, Flamini, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase HP-5HP-5DB-5DB-5HP-5
Column length (m) 30.30.30.30.30.
Carrier gas N2N2HeHeHe
Substrate      
Column diameter (mm) 0.250.250.250.250.25
Phase thickness (μm) 0.250.250.250.250.25
Tstart (C) 60.60.60.60.60.
Tend (C) 220.220.240.240.280.
Heat rate (K/min) 5.5.3.3.3.
Initial hold (min) 10.10.   
Final hold (min)      
I 1381.1382.1381.1383.1381.
ReferenceCampeol, Flamini, et al., 2003Dural, Bagci, et al., 2003Flamini, Cioni, et al., 2003Flamini, Luigi Cioni, et al., 2003Fokialakis, Melliou, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5MSSPB-5DB-5
Column length (m) 30.25.30.30.60.
Carrier gas  HeHeHeHe
Substrate      
Column diameter (mm) 0.320.250.250.250.25
Phase thickness (μm) 0.5 0.250.250.25
Tstart (C) 40.60.35.60.40.
Tend (C) 265.260.200.250.275.
Heat rate (K/min) 7.4.10.4.7.
Initial hold (min)   5.2. 
Final hold (min) 5. 30.20. 
I 1393.1385.1387.1381.1391.
ReferenceHögnadóttir and Rouseff, 2003Javidnia, Miri, et al., 2003Karagül-Yüceer, Vlahovich, et al., 2003Pino, Marbot, et al., 2003Valim, Rouseff, et al., 2003
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase SPB-1HP-5MSHP-5SPB-1DB-5
Column length (m) 30.30.30.37.30.
Carrier gas HeHe HeHe
Substrate      
Column diameter (mm) 0.200.250.250.320.32
Phase thickness (μm) 0.200.250.250.250.25
Tstart (C) 70.60.60.100.40.
Tend (C) 220.300.280.250.220.
Heat rate (K/min) 3.3.3.8.10.
Initial hold (min)   5. 5.
Final hold (min) 15.   30.
I 1357.1385.1379.1369.1389.
ReferenceCavaleiro, Salgueiro, et al., 2002Couladis, Chinou, et al., 2002Fokialakis, Magiatis, et al., 2002Misharina, Samusenko, et al., 2002Wu and Cadwallader, 2002
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5DB-5HP-5DB-5
Column length (m) 30.15.15.30.30.
Carrier gas He  HeHe
Substrate      
Column diameter (mm) 0.320.320.320.250.32
Phase thickness (μm) 0.250.50.50.250.5
Tstart (C) 40.30.30.60.33.
Tend (C) 220.225.225.280.230.
Heat rate (K/min) 10.10.10.3.8.
Initial hold (min) 5.2.2.5.5.
Final hold (min) 30.20.20. 8.
I 1388.1374.1408.1381.1365.
ReferenceWu and Cadwallader, 2002Zhou, Wintersteen, et al., 2002Zhou, Wintersteen, et al., 2002Aligiannis, Kalpoutzakis, et al., 2001Bezman, Rouseff, et al., 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-5HP-5DB-5CP Sil 5 CB
Column length (m) 30.30.30.30.50.
Carrier gas HeHeHe He
Substrate      
Column diameter (mm) 0.320.320.250.320.32
Phase thickness (μm) 0.50.50.250.250.4
Tstart (C) 33.33.60.35.60.
Tend (C) 230.230.380.200.280.
Heat rate (K/min) 8.8.3.10.3.
Initial hold (min) 5.5. 5.10.
Final hold (min) 8.8. 30.60.
I 1366.1368.1376.1370.1362.
ReferenceBezman, Rouseff, et al., 2001Bezman, Rouseff, et al., 2001Couladis, Tsortanidou, et al., 2001Karagül-Yüceer, Drake, et al., 2001Pino and Marbot, 2001
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase DB-5DB-1OV-101OV-101OV-101
Column length (m) 30.30.15.15.15.
Carrier gas H2N2   
Substrate      
Column diameter (mm) 0.320.320.320.320.32
Phase thickness (μm) 1.0.25   
Tstart (C) 40.150.35.35.35.
Tend (C) 220.280.250.250.250.
Heat rate (K/min) 3.3.6.6.6.
Initial hold (min)   3.3.3.
Final hold (min)      
I 1390.1373.1356.1356.1358.
ReferenceMoio L., Rillo L., et al., 1996Coen, Engel, et al., 1995Chisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillaryCapillaryCapillary
Active phase OV-101OV-101OV-101OV-101OV-101
Column length (m) 15.15.15.15.15.
Carrier gas      
Substrate      
Column diameter (mm) 0.320.320.320.320.32
Phase thickness (μm)      
Tstart (C) 35.35.35.35.35.
Tend (C) 250.250.250.250.250.
Heat rate (K/min) 6.6.6.6.6.
Initial hold (min) 3.3.3.3.3.
Final hold (min)      
I 1359.1359.1360.1360.1360.
ReferenceChisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994
Comment MSDC-RI MSDC-RI MSDC-RI MSDC-RI MSDC-RI
Column type CapillaryCapillaryCapillary
Active phase OV-101OV-101SPB-1
Column length (m) 15.15.15.
Carrier gas   He
Substrate    
Column diameter (mm) 0.320.320.32
Phase thickness (μm)   0.25
Tstart (C) 35.35.35.
Tend (C) 250.250.250.
Heat rate (K/min) 6.6.6.
Initial hold (min) 3.3.3.
Final hold (min)    
I 1364.1364.1368.
ReferenceChisholm, Guiher, et al., 1994Chisholm, Guiher, et al., 1994Chisholm and Samuels, 1992
Comment MSDC-RI MSDC-RI MSDC-RI

References

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

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Notes

Go To: Top, Van Den Dool and Kratz RI, non-polar column, temperature ramp, References