Molybdenum tetrafluoride
- Formula: F4Mo
- Molecular weight: 171.95
- CAS Registry Number: 23412-45-5
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: John E. Bartmess
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Individual Reactions
+ F4Mo = (
• F4Mo)
By formula: F- + F4Mo = (F- • F4Mo)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 383. ± 14. | kJ/mol | TDEq | Borshchevskii, Boltalina, et al., 1988 | gas phase; value altered from reference due to conversion from electron convention to ion convention |
| ΔrH° | 384. ± 17. | kJ/mol | TDEq | Borchevsky and Sidorov, 1985 | gas phase; Fluoride Affinity: MoF4 > UF4 by 7.1 kcal/mol; value altered from reference due to conversion from electron convention to ion convention |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N.,
Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions.,
J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8
. [all data]
Borchevsky and Sidorov, 1985
Borchevsky, A.Ya.; Sidorov, L.N.,
Ion-Molecule, Ion-Ion, and Molecule-Molecule Equilibria in the System Mo-U-Fe-F-O-e-,
Dokl. Akad. Nauk SSSR Ser. Khim., 1985, 285, 377. [all data]
Notes
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- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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