4-(Trifluoromethyl)phenylacetonitrile

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Robert L. Brown and Stephen E. Stein

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference
383. to 385.0.016PCR Inc., 1990

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C9H5F3N- + Hydrogen cation = 4-(Trifluoromethyl)phenylacetonitrile

By formula: C9H5F3N- + H+ = C9H6F3N

Quantity Value Units Method Reference Comment
Δr1420. ± 10.kJ/molG+TSTaft and Topsom, 1987gas phase
Quantity Value Units Method Reference Comment
Δr1393. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

De-protonation reactions

C9H5F3N- + Hydrogen cation = 4-(Trifluoromethyl)phenylacetonitrile

By formula: C9H5F3N- + H+ = C9H6F3N

Quantity Value Units Method Reference Comment
Δr1420. ± 10.kJ/molG+TSTaft and Topsom, 1987gas phase
Quantity Value Units Method Reference Comment
Δr1393. ± 8.4kJ/molIMRETaft and Topsom, 1987gas phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Taft and Topsom, 1987
Taft, R.W.; Topsom, R.D., The Nature and Analysis of Substituent Effects, Prog. Phys. Org. Chem., 1987, 16, 1. [all data]


Notes

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References