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pyrrolide anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

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Clustering reactions

pyrrolide anion + Methyl Alcohol = (pyrrolide anion bullet Methyl Alcohol)

By formula: C4H4N- + CH4O = (C4H4N- bullet CH4O)

Quantity Value Units Method Reference Comment
Deltar77.8 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar43.5 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

pyrrolide anion + Acetonitrile = (pyrrolide anion bullet Acetonitrile)

By formula: C4H4N- + C2H3N = (C4H4N- bullet C2H3N)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

pyrrolide anion + Formamide, N-methyl- = (pyrrolide anion bullet Formamide, N-methyl-)

By formula: C4H4N- + C2H5NO = (C4H4N- bullet C2H5NO)

Quantity Value Units Method Reference Comment
Deltar110. ± 8.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

pyrrolide anion + Acetone = (pyrrolide anion bullet Acetone)

By formula: C4H4N- + C3H6O = (C4H4N- bullet C3H6O)

Quantity Value Units Method Reference Comment
Deltar54.8 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar29. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

(pyrrolide anion bullet Acetone) + Acetone = (pyrrolide anion bullet 2Acetone)

By formula: (C4H4N- bullet C3H6O) + C3H6O = (C4H4N- bullet 2C3H6O)

Quantity Value Units Method Reference Comment
Deltar44.8kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSMeot-ner, 1988gas phase; M

pyrrolide anion + Acetamide, N-methyl- = (pyrrolide anion bullet Acetamide, N-methyl-)

By formula: C4H4N- + C3H7NO = (C4H4N- bullet C3H7NO)

Quantity Value Units Method Reference Comment
Deltar110.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
49.8497.PHPMSMeot-Ner (Mautner), 1988gas phase; M

pyrrolide anion + Pyrrole = (pyrrolide anion bullet Pyrrole)

By formula: C4H4N- + C4H5N = (C4H4N- bullet C4H5N)

Quantity Value Units Method Reference Comment
Deltar111. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar147.J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar68.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

(pyrrolide anion bullet Pyrrole) + Pyrrole = (pyrrolide anion bullet 2Pyrrole)

By formula: (C4H4N- bullet C4H5N) + C4H5N = (C4H4N- bullet 2C4H5N)

Quantity Value Units Method Reference Comment
Deltar71.5kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar131.J/mol*KPHPMSMeot-ner, 1988gas phase; M

pyrrolide anion + Water = (pyrrolide anion bullet Water)

By formula: C4H4N- + H2O = (C4H4N- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar65.7 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.7J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

(pyrrolide anion bullet Water) + Water = (pyrrolide anion bullet 2Water)

By formula: (C4H4N- bullet H2O) + H2O = (C4H4N- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar50.6kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSMeot-ner, 1988gas phase; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Meot-ner, 1988
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

Meot-Ner (Mautner), 1988
Meot-Ner (Mautner), M., Models for Strong Interactions in Proteins and Enzymes. 2. Interactions of Ions with the Peptide Link and Imidazole, J. Am. Chem. Soc., 1988, 110, 10, 3075, https://doi.org/10.1021/ja00218a014 . [all data]


Notes

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