Cyclohexane, 1,1'-ethylidenebis-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δcliquid-1995.kcal/molCcbSerijan and Wise, 1951Corresponding Δfliquid = -210. kcal/mol (simple calculation by NIST; no Washburn corrections); ALS
Δcliquid-2134.1kcal/molCcbWise, Serijan, et al., 1951Corresponding Δfliquid = -70.7 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
83.20313.Gudinowicz, Campbell, et al., 1963T = 313 to 483 K.; DH

Phase change data

Go To: Top, Condensed phase thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil544.32KN/ASerijan and Wise, 1951, 2Uncertainty assigned by TRC = 0.3 K; TRC
Tboil544.32KN/AWise, Serijan, et al., 1950Uncertainty assigned by TRC = 1. K; TRC
Tboil530.KN/ASabatier and Murat, 1915Uncertainty assigned by TRC = 10. K; TRC
Tboil530.KN/ASabatier and Murat, 1912Uncertainty assigned by TRC = 10. K; TRC
Quantity Value Units Method Reference Comment
Tfus252.28KN/ASerijan and Wise, 1951, 3Uncertainty assigned by TRC = 0.3 K; TRC
Tfus252.28KN/ASerijan and Wise, 1951, 2Uncertainty assigned by TRC = 0.2 K; TRC
Tfus252.17KN/AWise, Serijan, et al., 1950Uncertainty assigned by TRC = 0.7 K; TRC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
14.8385.AStephenson and Malanowski, 1987Based on data from 370. to 402. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 22365

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Serijan and Wise, 1951
Serijan, K.T.; Wise, P.H., Dicyclic hydrocarbons. III. Diphenyl- and dicyclohexylalkanes through C15, J. Am. Chem. Soc., 1951, 73, 4766-4769. [all data]

Wise, Serijan, et al., 1951
Wise, C.H.; Serijan, K.T.; Goodman, I.A., NACA Technical Report 1003, NACA Technical Report 1003, 1951, 1-10. [all data]

Gudinowicz, Campbell, et al., 1963
Gudinowicz, B.J.; Campbell, R.H.; Adams, J.S., Specific heat measurements of complex saturated hydrocarbons, J. Chem. Eng. Data, 1963, 8, 201-214. [all data]

Serijan and Wise, 1951, 2
Serijan, K.T.; Wise, P.H., Dicylic Hydrocarbons. III. Diphenyl- and Dicyclohexylalkanes through C15, J. Am. Chem. Soc., 1951, 73, 4766. [all data]

Wise, Serijan, et al., 1950
Wise, P.H.; Serijan, K.T.; Goodman, I.A., Correlation of Physical Properties with Molecular Structre for Dicyclic Hydrocarbons. I. 2-n-Alakylbiphenyl-1,1-alkane, α,ω-dicyclohexylalkane Series, Nat. Advis. Comm. Aeronaut., Tech. Notes, No. 2081, Lewis Flight Propulsion Lab., Cleveland, OH, 1950. [all data]

Sabatier and Murat, 1915
Sabatier, P.; Murat, M., Ann. Chim. (Paris), 1915, 4, 253. [all data]

Sabatier and Murat, 1912
Sabatier, P.; Murat, M., C. R. Hebd. Seances Acad. Sci., 1912, 154, 1771. [all data]

Serijan and Wise, 1951, 3
Serijan, K.T.; Wise, P.H., , Natl. Advis. Comm. Aeronaut., Lewis Flight Propulsion Lab ., Cleveland, 1951. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References